65425-95-8Relevant academic research and scientific papers
Stereoselective synthesis of (E)-α-halovinylsilanes via hydrozirconation of alkynylsilanes
Cai, Ming-Zhong,Huang, Jia-Di,Ye, Xin-Lin,Song, Cai-Sheng
, p. 770 - 771 (2007/10/03)
Hydrozirconation of alkynylsilanes 1 at room temperature in THF gave the (E)-α- silylvinylzirconium complexes 3, which were reacted with NBS or iodine to afford stereoselectively (E)-α-halovinylsilanes 4 in good yields.
