655229-87-1

Upstream product

• 655230-45-8 (2-azido-5-bromophenyl)methanol 
• 20615-76-3 2-azidobenzyl alcohol 

Downstream Products

• 655229-97-3 dithiocarbonic acid O-ethyl ester S-(2-azido-5-bromobenzyl) ester 
• 946120-14-5 2-azido-5-bromobenzyl azide 
• 946120-19-0 C₄₃H₃₅BrN₂P₂ 
• 1219081-15-8 1-[(2-azido-5-bromo)phenylmethyl]-1H-benzotriazole 
• 1219081-25-0 2-[(2-azido-5-bromo)phenylmethyl]-2H-benzotriazole 
• 655230-14-1 dithiocarbonic acid O-ethyl ester S-(5-bromo-2-triphenylphosphoranylideneamino)benzyl ester 
• 566942-93-6 dithiocarbonic acid S-(5-bromo-2-diphenylvinylideneamino-benzyl) ester O-ethyl ester 

Relevant academic research and scientific papers

N-butyllithium-mediated reactions of 1-(2-azidoarylmethyl)-1H- benzotriazoles with alkyl halides

(Chemical Equation Presented) Treatment of 1-(2-azidoarylmethyl)-1H- benzotriazoles (6) with n-BuLi (2.5 equiv.) in THF at -78°C, followed by an addition of alkyl halides such as allyl, benzyl, and ethyl bromides with stirring for 2 h at room temperature afforded 2-(dialkylamino)-3-(benzotriazol- 1-yl)-2H-indazoles (8), 3-(benzotriazol-1-yl)-2H-indazoles (9), 2-[(benzotriazol-1-yl)methyl]arylamine (10), and 2-[(benzotriazol-1-yl)(alkyl) methyl]arylamine (11).

Intramolecular addition of benzylic radicals onto ketenimines. Synthesis of 2-alkylindoles

The inter- and intramolecular addition of free radicals onto ketenimines is studied. All the attempts to add intermolecularly several silicon, oxygen or carbon centered radicals to N-(4-methylphenyl)-C,C-diphenyl ketenimine were unsuccessful. In contrast, the intramolecular addition of benzylic radicals, generated from xanthates, onto the central carbon of a ketenimine function with its N atom linked to the ortho position of the aromatic ring occurred under a variety of reaction conditions. These intramolecular cyclizations provide a novel radical-mediated synthesis of 2-alkylindoles.