655243-52-0Relevant academic research and scientific papers
Synthesis of tertiary α-hydroxy acids by silylene transfer to α-keto esters
Howard, Brett E.,Woerpel
, p. 4651 - 4653 (2007)
(Chemical Equation Presented) α-Keto esters can be converted into α-hydroxy acids in a single flask involving metal-catalyzed silylene transfer, 6π-electrocyclization, Ireland-Claisen rearrangement, and hydrolysis. This reaction sequence is stereoselectiv
α-Oximono-esters as precursors to heterocycles - generation of oxazinone N-oxides and cycloaddition to alkene dipolarophiles
Heaney, Frances,Fenlon, Julie,O'Mahony, Colm,McArdle, Patrick,Cunningham, Desmond
, p. 4302 - 4316 (2007/10/03)
Preparation of a series of terminally and internally substituted δ-alkenyl and δ-alkynyl esters 6,7 and 9, potential precursors to oxazin-2-one nitrones, has been attempted. Condensation between pyruvic or benzoylformic acid and the appropriate alcohol pr
