65530-43-0Relevant academic research and scientific papers
Hydroamination of terminal alkynes with secondary amines catalyzed by copper: Regioselective access to amines
Bahri, Janet,Blieck, Rémi,Jamoussi, Bassem,Taillefer, Marc,Monnier, Florian
supporting information, p. 11210 - 11212 (2015/07/07)
A simple and convenient copper-catalyzed hydroamination of arylacetylenes with secondary amines has been performed giving a simple access to aliphatic amines after reduction of the hydroaminated products (E-enamines). Here we described a mild catalytic system utilizing CuCN precatalyst without any additive ligands in a solvent-free system.
A mild one-pot conversion of alkenes into amines through tandem ozonolysis and reductive amination
Kyasa, Shivakumar,Fisher, Thomas J.,Dussault, Patrick H.
experimental part, p. 3475 - 3481 (2011/12/04)
The selective reduction of hydroperoxyacetals to aldehydes by sodium triacetoxyborohydride provides the basis for a mild one-pot synthesis of amines from alkenes. Georg Thieme Verlag Stuttgart.
A New and Convenient Synthesis of N-Substituted Perhydroazepines from Adipaldehyde and Primary Amines with Tetracarbonylhydridoferrate, HFe(CO)4-, as a Selective Reducing Agent
Shim, Sang Chul,Doh, Chil Hoon,Kim, Tae Jeong,Lee, Hak Ki,Kim, Ki Doo
, p. 1383 - 1385 (2007/10/02)
Ethanolic tetracarbonylhydridoferrate combined with adipaldehyde is very efficient for the selective transformation of an amino group into perhydroazepine.A large variety of both aliphatic and aromatic amines react with adipaldehyde in the presence of tetracarbonylhydridoferrate at room temperature and carbon monoxide to give the corresponding N-alkyl- and N-arylperhydroazepines in good to excellent yields.
