6555-58-4

Basic information

• Product Name: 1β-Acetyl-4β-t-butyl-1α-cyclohexanol
• Synonyms: 1β-Acetyl-4β-t-butyl-1α-cyclohexanol
• CAS NO: 6555-58-4
• Molecular Weight: 198.305
• Mol File: 6555-58-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1β-Acetyl-4β-t-butyl-1α-cyclohexanol(CAS DataBase Reference)
• NIST Chemistry Reference: 1β-Acetyl-4β-t-butyl-1α-cyclohexanol(6555-58-4)
• EPA Substance Registry System: 1β-Acetyl-4β-t-butyl-1α-cyclohexanol(6555-58-4)

Safety Data

• Hazardous Substances Data: 6555-58-4(Hazardous Substances Data)

Upstream product

• 98-53-3 4-tercbutyl-cyclohexanone 
• 75-05-8 acetonitrile 

Downstream Products

• 25143-76-4 trans-4-t-butyl-1-ethyl-1-cyclohexanol 
• 134023-81-7 1-(1-Amino-ethyl)-4-tert-butyl-cyclohexanol 

Relevant articles and documents

Electroorganic Chemistry. 140. Electroreductively Intra- and Intermolecular Couplings of Ketones with Nitriles

Electroreduction of γ- and δ-cyano ketones in i-PrOH with Sn cathode gave α-hydroxy ketones and their dehydroxylated ketones as the intramolecularly coupled products.Guaiazulene, (-)-valeranone, polyquinanes, dihydrojasmone, methyl dihydrojasmonate, and rosaprostol have been synthesized by utilizing this electroreductive intramolecular coupling of γ- and δ-cyano ketones in one of the key steps.Similarly, electroreduction of a mixture of ketone and nitrile gave the corresponding intermolecularly coupled product.The product obtained by the electroreductive intermolecular coupling of (+)-dihydrocarvone with acetonitrile has been found to be the precursor of an effective chiral ligand for the enantioselective addition of diethylzinc to aldehydes.