65565-12-0

Basic information

• Product Name: 1-Propanone, 3-(3-bromophenyl)-1-phenyl-
• CAS NO: 65565-12-0
• Molecular Formula: C15H13BrO
• Molecular Weight: 289.172
• Mol File: 65565-12-0.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1-Propanone, 3-(3-bromophenyl)-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanone, 3-(3-bromophenyl)-1-phenyl-(65565-12-0)
• EPA Substance Registry System: 1-Propanone, 3-(3-bromophenyl)-1-phenyl-(65565-12-0)

Safety Data

• Hazardous Substances Data: 65565-12-0(Hazardous Substances Data)

Upstream product

• 937375-28-5 3-(3-bromophenyl)-N-methoxy-N-methylpropanamide 
• 100-58-3 phenylmagnesium bromide 
• 98-85-1 1-Phenylethanol 
• 15852-73-0 (3-Bromophenyl)methanol 
• 58084-06-3 3-(3-bromophenyl)-1-phenylprop-2-yn-1-one 
• 98-86-2 acetophenone 
• 29816-74-8 (E)-3-(3-bromophenyl)-1-phenyl-2-propen-1-one 
• 29816-74-8 3-(3-bromophenyl)-1-phenylprop-2-en-1-one 

Downstream Products

• 937375-29-6 5-[2-(3-bromophenyl)ethyl]-5-phenylimidazolidine-2,4-dione 

Relevant articles and documents

Electrochemical-Induced Hydrogenation of Electron-Deficient Internal Olefins and Alkynes with CH3OH as Hydrogen Donor

Efficient hydrogenation of electron-deficient internal olefins and alkynes access to saturate ketone with CH3OH as a single hydrogen donor under electrochemical conditions has been successfully developed. This hydrogenation strategy can be used to convert electron-deficient internal olefins and alkynes to saturate ketone under electrochemical conditions with exogenous-reductant and a metal catalyst. Mechanistic studies reveal that radical hydrogenation was involved in this transformation. Notably, various electron-deficient internal olefins and alkynes could be tolerated in such an electrochemical hydrogenation synthetic strategy and can be easily scaled up with good efficiency. (Figure presented.).

Aldehyde-catalyzed transition metal-free dehydrative β-alkylation of methyl carbinols with alcohols

Different to the borrowing hydrogen strategy in which alcohols were activated by transition metal-catalyzed anaerobic dehydrogenation, the direct addition of aldehydes was found to be an effective but simpler way of alcohol activation that can lead to efficient and green aldehyde-catalyzed transition metal-free dehydrative C-alkylation of methyl carbinols with alcohols. Mechanistic studies revealed that the reaction proceeds via in situ formation of ketones by Oppenauer oxidation of the methyl carbinols by external aldehydes, aldol condensation, and Meerwein-Ponndorf-Verley (MPV)-type reduction of α,β-unsatutated ketones by substrate alcohols, affording the useful long chain alcohols and generating aldehydes and ketones as the by-products that will be recovered in the next condensation to finish the catalytic cycle. Copyright

Selective 1,4-reduction of chalcones with Zn/NH4Cl/C 2H5OH/H2O

In this paper, the Zn/NH4Cl/C2H5OH/H 2O system was applied for the selective 1,4-reduction of chalcones undermild conditions with high selectivity. Themerit lies in inexpensive reagent, simple operation and envi