65595-02-0Relevant articles and documents
COMPOUNDS, COMPOSITIONS AND METHODS FOR SYNTHESIS
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, (2019/01/10)
The present disclosure, among other things, provides technologies for synthesis, including reagents and methods for stereoselective synthesis. In some embodiments, the present disclosure provides compounds useful as chiral auxiliaries. In some embodiments, the present disclosure provides reagents and methods for oligonucleotide synthesis. In some embodiments, the present disclosure provides reagents and methods for chirally controlled preparation of oligonucleotides. In some embodiments, technologies of the present disclosure are particularly useful for constructing challenging internucleotidic linkages, providing high yields and stereoselectivity.
Inter- and intramolecular addition reactions of electron-deficient alkenes with alkyl radicals, generated by SET-photochemical decarboxylation of carboxylic acids, serve as a mild and efficient method for the preparation of γ-amino acids and macrocyclic l
Yoshimi, Yasuharu,Masuda, Miho,Mizunashi, Tomoyuki,Nishikawa, Keisuke,Maeda, Kousuke,Koshida, Nobumasa,Itou, Tatsuya,Morita, Toshio,Hatanaka, Minoru
supporting information; experimental part, p. 4652 - 4655 (2009/12/24)
Inter- and Intramolecular additions of alkyl radicals, generated by SET photochemical decarboxylation reactions of free carboxylic acids, to electron-deficient alkenes take place under mild conditions as part of efficient routes for the formation of NBoc
A synthesis of the tetracyclic carboskeleton of isaindigotidione
Poon, Ch. Yan,Chiu, Pauline
, p. 2985 - 2988 (2007/10/03)
An efficient synthesis of the unique indolizino[7,6-c]quinoline carboskeleton of isaindigotidione has been achieved. This strategy employed L-proline and isatin as the main building blocks in the construction of the framework. Four transformations occurred in a one-pot operation to furnish the tetracyclic nucleus.