656-90-6

Basic information

• Product Name: Ethaneperoxoic acid, trifluoro-, 1,1-dimethylethyl ester
• CAS NO: 656-90-6
• Molecular Formula: C6H9F3O3
• Molecular Weight: 186.131
• Mol File: 656-90-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ethaneperoxoic acid, trifluoro-, 1,1-dimethylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Ethaneperoxoic acid, trifluoro-, 1,1-dimethylethyl ester(656-90-6)
• EPA Substance Registry System: Ethaneperoxoic acid, trifluoro-, 1,1-dimethylethyl ester(656-90-6)

Safety Data

• Hazardous Substances Data: 656-90-6(Hazardous Substances Data)

Upstream product

• 407-25-0 trifluoroacetic anhydride 
• 75-65-0 tert-butyl alcohol 

Downstream Products

• 75-72-9 chlorotrifluoromethane 
• 15719-64-9 methylammonium carbonate 
• 76-05-1 trifluoroacetic acid 
• 115-11-7 isobutene 

Relevant articles and documents

Oxidative Fragmentation of Saturated Hydrocarbons. II. Oxidative Fragmentation of 1,3,5-Trimethyladamantane

Oxidation of 1,3,5-trimethyladamantane and 7-hydroxy-1,3,5-trimethyladamantane by perfluoroperoxybutyric acid in perfluorobutyric acid is accompanied by fragmentation of the adamantane polyhedron with formation of cis-1,3,5-trimethyl-cis-3,5-bis(perfluorobutanoyloxymethyl)cyclohexaneacetic acid. The reaction of tert-butyl alcohol with perfluoroperoxyacetic acid simulates well the process of oxidative fragmentation of adamantane and its derivatives. The mechanisms of these transformations are discussed.