656252-34-5

Upstream product

• 137688-21-2 (-)-(S)-2-(but-3-enyl)oxirane 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 386703-30-6 1-[2-(tert-butyl-dimethyl-silanyloxymethyl)-3-methoxy-5-methyl-phenyl]-hex-5-en-2-ol 
• 386703-27-1 N-tert-butyl-2-(2-hydroxy-hex-5-enyl)-6-methoxy-4-methyl-benzamide 
• 386703-29-3 (S)-1-(2-Hydroxymethyl-3-methoxy-5-methyl-phenyl)-hex-5-en-2-ol 
• 386703-28-2 (S)-3-But-3-enyl-8-methoxy-6-methyl-isochroman-1-one 
• 386703-38-4 tert-butyl-[2-methoxy-6-(2-methoxymethoxy-hex-5-enyl)-4-methyl-benzyloxy]-dimethyl-silane 

Relevant academic research and scientific papers

Total Synthesis of Hamigerans and Analogues Thereof. Photochemical Generation and Diels-Alder Trapping of Hydroxy-o-quinodimethanes

A number of naturally occurring substances, including hamigerans, contain ring systems which are fused to an aromatic nucleus. A general and streamlined method for the construction of such benzannulated bi- and polycyclic carbon frameworks has been develo

Total synthesis of hamigerans: Part 1. Development of synthetic technology for the construction of benzannulated polycyclic systems by the intramolecular trapping of photogenerated hydroxy-o-quinodimethanes and synthesis of key building blocks

A streamlined and general method for the construction of benzannulated systems such as I involves the intramolecular Diels - Alder reaction of photochemically generated hydroxy-o-quinodimethanes, for example, II. The method was optimized to set the stage