65684-00-6Relevant academic research and scientific papers
Synthesis and stereochemical resolution of functional [5]pericyclynes
Maurette, Luc,Tedeschi, Christine,Sermot, Emmanuelle,Soleilhavoup, Michle,Hussain, Fatima,Donnadieu, Bruno,Chauvin, Remi
, p. 10077 - 10098 (2007/10/03)
Three different kinds of ring carbo-mers of [5]cyclitol ethers were targeted as challenging examples of functional [5]pericyclynes. Three tertiary pentaaryl-carbo-[5]cyclitol methyl ethers were synthesized through a [11+4] ring-closing double addition of
Synthesis of 2-Aryl-(2-R)-arsenines by Cyclohexadienol -> Arsabenzene Rearrangement
Maerkl, Gottfried,Liebl, Rainer,Baier, Horst
, p. 1610 - 1632 (2007/10/02)
KOH/crown-6 phase-transfer catalyzed addition of arylarsines (phenylarsine, p-tolylarsine) to the (3-R)-3-methoxy-1,4-pentadiynes 13 yields the cis/trans isomeric 1-aryl-1,4-dihydro-(4-R)-4-methoxyarsenines, the 1H-NMR- and 13C-NMR spectra of which ar
