65712-87-0

Usage

InChI:InChI=1/C6H10O3/c1-8-6-3-2-5(7)4-9-6/h6H,2-4H2,1H3

Upstream product

• 66302-69-0 2,5-dimethoxy-2,3,4,5-tetrahydrofurfuryl alcohol 
• 60249-17-4 6-methoxy-2H-pyran-3(6H)-one 
• 28194-32-3 6(R)-methoxy-3(S)-hydroxy-tetrahydro-2H-pyran 
• 4454-05-1 2-methoxy-3,4-dihydro-2H-pyran 

Downstream Products

• 130084-70-7 N-Cyclohexyl-5,6-dihydro-6-methoxy-2H-pyran-3(4H)-imin 
• 137303-94-7 C₁₃H₁₈N₂O₄S 
• 130084-55-8 3,4-Dihydro-2-methoxy-10-phenyl-2H-pyrano<3,2-b>chinolin 
• 259263-42-8 1-methoxy-4-phenethylenetetrahydropyran 
• 130084-71-8 5,6-Dihydro-4-(1-hydroxybenzyliden)-6-methoxy-2H-pyran-3(4H)-on 
• 130084-67-2 5,6-Dihydro-4-(1-hydroxybenzyl)-6-methoxy-2H-pyran-3(4H)-on 
• 130084-50-3 N-(3,4,5,6-Tetrahydro-6-methoxy-3-phenyl-2H-pyran-3-yl)-piperidin 
• 130084-56-9 3,4-Dihydro-2-hydroxy-10-phenyl-2H-pyrano<3,2-b>chinolin 
• 130084-57-0 2-Chlor-3,4-dihydro-10-phenyl-2H-pyrano<3,2-b>chinolin 
• 130084-72-9 5,8-Dihydro-6-methoxy-2,4-diphenyl-6H-pyrano<3,4-d>pyrimidin 
• 130084-69-4 5,6-Dihydro-4-(α-hydroxy-4-nitrobenzyl)-6-methoxy-2H-pyran-3(4H)-on 
• 130084-59-2 3-(3-Hydroxy-6-methyl-4-oxo-4H-pyran-2-yl)-propanal-p-nitrophenylhydrazon 
• 130084-68-3 Perhydro-6-methoxy-2,4-bis(p-nitrophenyl)pyrano<3,4-d>-<1,3>dioxin-8a-ol 
• 137303-95-8 C₁₃H₂₀N₂O₄S 

Relevant academic research and scientific papers

C-glycosylation reactions of sulfur-substituted glycosyl donors: Evidence against the role of neighboring-group participation

Nucleophilic substitution reactions of C-4 sulfur-substituted tetrahydropyran acetals revealed that neighboring-group participation does not control product formation. Spectroscopic evidence for the formation of an intermediate sulfonium ion is provided,

Beta-Amino-Acid derivatives as inhibitors of matrix metalloproteases and TNF-Alpha

The present application describes novel β-amino acid derivatives of formula I: or pharmaceutically acceptable salt or prodrug forms thereof, wherein A, X, Z, Ua, Xa, Ya, Za, R1, R2, R3, R4, and R4a are defined in the present specification, which are useful as metalloprotease and/or as TNF-α inhibitors.

Remote Control of Double Bond Stereochemistry in the Wadsworth-Emmons Reaction

Wadsworth-Emmons reactions of 6-methoxytetrahydropyran-3-one 2 and 5-arylthio-6-methoxytetrahydropyran-3-one 5 - 9 have been investigated and the ratio of (E)- and (Z)-α,β-unsaturated esters formed has been shown to be affected by the presence and type of arylthio substituent.

Improved Synthesis of Secondary Hydroperoxides from Alcohols

Secondary hydroperoxides have been prepared from secondary alcohols by conversion of the alcohol into its mesylate and subsequent reaction with anhydrous hydrazine followed by hydrogen peroxide and sodium peroxide.

SYNTHESIS OF 2-SUBSTITUTED 3-FORMYL-5-METHOXYTETRAHYDROFURANS FROM 2,5-DIMETHOXYTETRAHYDROFURYL-3-CARBINOLS

The acid-catalyzed rearrangement of 2,5-dimethoxytetrahydrofuryl-3-carbinol, obtained from 2,5-dimethoxy-3-formyltetrahydrofuran, gave the 2-substituted 3-formyl-5-methoxytetrahydrofuran.