4454-05-1Relevant articles and documents
PRODUCTION PROCESS OF TETRAHYDROPYRAN COMPOUND AND TETRAHYDROPYRAN COMPOUND PRODUCED BY THE PRODUCTION PROCESS
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Page/Page column 25, (2008/06/13)
The invention provides a production process of a tetrahydropyran compound, characterized by allowing 3,4-dihydro-2-alkoxy-2H-pyran compound or tetrahydro-2-alkoxy-2H-pyran compound which can be easily prepared through reaction between acrolein and alkylvinylether, with hydrogen in the presence of a catalyst containing an element of Groups VIII to X under acidic condition. The production process of the invention is useful for production of Grignard reaction solvent or polymer solvent and intermediate of organic compound.
VINYL ETHER DERIVATIVES
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, (2008/06/13)
Processes for the manufacture of vinyl ether derivatives, e.g., methoxydihydropyran, are disclosed which comprise reacting acetylene and a lower alcohol, e.g., methanol, to form a vinyl alkyl ether, e.g., vinyl methyl ether, reacting the vinyl alkyl ether so produced with an alpha , beta -unsaturated carbonylic compound, e.g., acrolein, in the presence of the lower alcohol to preferably enhance the conversion of the vinyl alkyl ether to the vinyl ether derivative. In one aspect of the invention, the vinyl ether derivative is methoxydihydropyran which is subjected to hydrolysis to form glutaraldehyde.
Ozonolysis of Symmetrically 1,2-Disubstituted Ethylenes in HCl/Methanol Solutions: Acid Catalyzed Reactions of Primary Cleavage Products
Griesbaum, Karl,Neumeister, Joachim
, p. 2697 - 2706 (2007/10/02)
The ozonolysis of olefins in 1 M anhydrous solutions of hydrogen chloride in methanol at /= 0 deg C was investigated.Upon warm-up of the ozonolysis products, the peroxidic primary fragmentation products were converted into non peroxidic end-products by HCl-catalyzed reactions.Cyclopentene (1a) and cyclohexene (1b), e.g., afforded mixtures of the corresponding α,ω-dialdehydebis(dimethyl acetals) (8), dimethyl α,ω-dicarboxylates (9), and methyl ω-aldehyde dimethyl acetal carboxylates (10).Norbornene (1c) gave a mixture of the correspondingly substituted 1,3-cyclopentane compounds (8c - 10c), phenanthrene (22) gave a mixture of methyl 2'-formyl-2-biphenylcarboxylate (24a), 2,2'-biphenyldicarbaldehyde (24b), and dimethyl 2,2'-biphenyldicarboxylate (24c).A reaction scheme was advanced for the rationalization of the types and the distribution of the products.It was partly substantiated by model reactions.