6573-11-1

Basic information

• Product Name: 1,4,7-TRITHIACYCLONONANE
• Synonyms: 1,4,7-TRITHIACYCLONONANE;TRIETHYLENE TRISULFIDE;[9]aneS3;Hexahydro-1,4,7-trithionin;1,4,7-Trithiacyclononane,Triethylene trisulfide;1,4,7-Trithiacyclononane 97%;1,4,7-trithionane
• CAS NO: 6573-11-1
• Molecular Formula: C₆H₁₂S₃
• Molecular Weight: 180.35
• Product Categories: Crown Ethers;Functional Materials;Macrocycles for Host-Guest Chemistry
• Mol File: 6573-11-1.mol
• Article Data: 2

Chemical Properties

• Melting Point: 78-81 °C(lit.)
• Boiling Point: 308.6°C at 760 mmHg
• Flash Point: 149.3°C
• Appearance: /
• Density: 1.14g/cm³
• Vapor Pressure: 0.00123mmHg at 25°C
• Refractive Index: 1.573
• BRN: 1616445
• CAS DataBase Reference: 1,4,7-TRITHIACYCLONONANE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4,7-TRITHIACYCLONONANE(6573-11-1)
• EPA Substance Registry System: 1,4,7-TRITHIACYCLONONANE(6573-11-1)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 6573-11-1(Hazardous Substances Data)

Usage

Uses

1,4,7-Trithiacyclononane (9S3) is a tridentate thioether ligand that can be used to prepare complexes with a wide variety of transition metal ions. These complexes often possess exceptional electronic and redox properties. 9S3 ligand reacts with palladium metal ion to form palladium(II) thioether complex, which is used as a catalyst in the C-H activation reactions. Manganese complex of 9S3 ligand is employed as a catalyst for the oxidation of olefins, alkanes, and alcohols.

InChI:InChI=1/C6H12S3/c1-2-8-5-6-9-4-3-7-1/h1-6H2

Upstream product

• 92314-36-8 bis(tetramethylammonium) 3-thiapentane-1,5-dithiolate 
• 106-93-4 ethylene dibromide 

Downstream Products

• 141713-38-4 {RuH(CS)PPh₃(1,4,7-tetrathiacyclononane)}ClO₄ 
• 141713-36-2 {RuCl(CS)PPh₃(1,4,7-tetrathiacyclononane)}ClO₄ 
• 158239-21-5 [(1,4,7-trithiacyclononane)(ethene)(P(C₆H₁₁)3)rhodium(I)]PF₆ 
• 142417-94-5 RuCl(P(CH₃)2C₆H₅)2C₆H₁₂S₃⁽¹⁺⁾ 
• 142417-95-6 {RuCl(P(C₂H₅)2C₆H₅)2C₆H₁₂S₃}⁽¹⁺⁾ 
• 145312-34-1 RuCl(CO)(P(C₆H₅)3)(C₆H₁₂S₃)⁽¹⁺⁾*PF₆^(1-)=(RuCl(CO)(P(C₆H₅)3)(C₆H₁₂S₃))PF₆ 

Relevant articles and documents

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