65756-27-6Relevant academic research and scientific papers
Easy synthesis of 7-alkylbicyclo[3.3.1]non-6-en-3-ones by silica gelpromoted fragmentation of 3-alkyl-2-oxaadamant-1-yl mesylates
Camps, Pelayo,El Achab, Rachid,Font-Bardia, Merce,Goerbig, Diana,Morral, Jordi,Munoz-Torrero, Diego,Solans, Xavier,Simon, Montserrat
, p. 5867 - 5880 (2007/10/03)
A synthesis of 7-alkylbicyclo[3.3.1]non-6-en-3-ones 4b-f and 4j,k by reaction of the corresponding 3-alkyl-2-oxaadamant-1-yl mesylates 3 with silica gel in methylene chloride at room temperature, is described. The method failed to give enones 4a,g and the
Direct Clay-Catalyzed Friedel-Crafts Arylation and Chlorination of the Hydrocarbon Adamantane
Chalais, Stephane,Cornelis, Andre,Gerstmans, Andre,Kolodziejski, Waclaw,Laszlo, Pierre,et al.
, p. 1196 - 1203 (2007/10/02)
Multiple chlorinations and arylations at the tertiary positions of adamantane are promoted by FeCl3-doped K10 montmorillonite in CCl4 or in aromatic solvents.The process, remarkably easy implement, can be tailored to selective formation of monosubstituted 1-adamantyl derivatives or 1,3-disubstituted adamantanes.The process achieves alkylation at the meta- and para-positions of toluene leading to a purely statistical distribution and displays no substrate specificity in competition experiments between toluene and benzene.
REACTIONS OF ADAMANTYL NITRATES WITH AROMATIC COMPOUNDS.
Moiseev, I. K.,Doroshenko, R. I.
, p. 1067 - 1069 (2007/10/02)
It has been shown to be possible to use adamantyl nitrates in the synthesis of mono- and diaryladamantanes.The effects of substituents and the acidity of the medium on the yields of reaction products have been studied.
