65788-85-4Relevant academic research and scientific papers
Novel synthesis of allyl and cyclopropylcarbinyl thiocyanates by the reaction of organocobaloximes with thiocyanogen
Gupta,Mandal, Debprasad,Dixit, Vandana
, p. 970 - 972 (2007/10/03)
Thiocyanogen reacts in aprotic solvents with allyl and but-3-enyl cobaloximes to give moderate yields of allyl and cyclopro-pylcarbinyl thiocyanates. Using this method highly unstable allyl thiocyanates may be prepared in situ at low temperature. Their rearrangement to isothiocyanates is observed at sub-zero temperatures.
