65796-64-7Relevant academic research and scientific papers
Iminophosphanes: Synthesis, Rhodium Complexes, and Ruthenium(II)-Catalyzed Hydration of Nitriles
Rong, Mark K.,Van Duin, Koen,Van Dijk, Tom,De Pater, Jeroen J. M.,Deelman, Berth-Jan,Nieger, Martin,Ehlers,Slootweg, J. Chris,Lammertsma, Koop
supporting information, p. 1079 - 1090 (2017/04/21)
Highly stable iminophosphanes, obtained from alkylating nitriles and reaction of the resulting nitrilium ions with secondary phosphanes, were explored as tunable P-monodentate and 1,3-P,N bidentate ligands in rhodium complexes. X-ray crystal structures ar
162. Transition Metal Complexes with Bidentate Ligands Spanning trans-Position. XII. Steric Effects in the Kinetics and Mechanism of Substitutions at Hydride and Methyl Bisphosphine Platinum(II) Complexes
Elding, Lars I.,Kellenberger, Bruno,Venanzi, Luigi M.
, p. 1676 - 1690 (2007/10/02)
Ligand substitution reactions on square-planar platinum(II) compolexes of the types trans-, trans-, trans- (R=H, Me; X=Cl-, I-,; L=PEt3, bis(3-trifluoromethylpheny
Asymmetric Hydroformylation of Vinyl Acetate with DIOP-Type Ligands
Hobbs, Charles F.,Knowles, W. S.
, p. 4422 - 4427 (2007/10/02)
The rhodium-catalyzed hydroformylation of vinyl acetate and related esters was carried out in the presence of chiral phosphine ligands of the DIOP type to give the corresponding optically active 2-(acyloxy)propanal, a precursor for the amino acid threonine.Ligand structure and the ligand/metal ratio were the primary factors controlling asymmetric induction; temperature, CO pressure, and solvent polarity had minor effects.The highest induction efficiencies, up to 51 percent ee, were obtained with the 5H-dibenzophospholyl derivative of DIOP (DIPHOL, 1e).
