65817-73-4Relevant academic research and scientific papers
On the Reaction of Aminoxyls with Dioxiranes
Dinoi, Anna,Curci, Ruggero,Carloni, Patricia,Damiani, Elisabetta,Stipa, Pierluigi,Greci, Lucedio
, p. 871 - 876 (2007/10/03)
In the reactions of dimethyldioxirane (1a) and methyl(trifluoromethyl)dioxirane (1b) with 2,2,6,6-tetramethylpiperidinyl-1-oxyl (2) (TEMPO) in acetone, the corresponding methoxyamine 1-methoxy-2,2,6,6-tetramethylpiperidine (5) is produced in ≥98% yield, b
HOMOLYTIC SUBSTITUTIONS IN INDOLINONE NITROXIDE RADICALS-III REACTIONS WITH TERBUTOXY AND METHYL RADICALS
Greci, L.
, p. 2435 - 2440 (2007/10/02)
Nitroxide radicals 1a-c react with terbutoxy radical to form terbutoxy substituted radicals 2, 3 and 4.The reaction mechanism is interpreted in terms of homolytic substitution.The terbutoxy substituted nitroxides can be easily oxidized to quinoneimine N-o
