65832-84-0Relevant academic research and scientific papers
Synthesis of lithium 1-alkynesulfenates by the mild oxidation of thiolates with a pinacolone-derived N-sulfonyloxaziridine
Sandrinelli, Franck,Boudou, Cédric,Caupène, Caroline,Averbuch-Pouchot, Marie-Thérèse,Perrio, Stéphane,Metzner, Patrick
, p. 3289 - 3293 (2008/09/18)
Lithium 1-alkynethiolates, generated by a base-induced ring cleavage of 4-substituted 1,2,3-thiadiazoles, were efficiently converted into the corresponding sulfenate salts by mild oxidation using an N-sulfonyloxaziridine derived from pinacolone. In situ S
