65864-59-7

Upstream product

• 96996-90-6 1,2,3,4,6-penta-O-benzoyl-α,β-D-mannopyranoside 
• 14218-11-2 2,3,4,6-Tetra-O-benzoyl-α-D-mannopyranosyl bromide 

Downstream Products

• 1158796-24-7 1-(2,3,4,6-tetra-O-benzoyl-α-D-mannosyl)-1H-benzo[d][1,2,3]triazole 
• 639464-28-1 2,4-di-O-benzoyl-α-D-mannopyranosyl azide 
• 674302-92-2 allyl 3,4,6-tri-O-benzyl-2-deoxy-2-[N'-(2',3',4',6'-tetra-O-benzoyl-β-D-mannopyranosyl)ureido]-β-D-mannopyranoside 
• 674302-91-1 methyl 2,3,4-tri-O-benzyl-6-deoxy-6-[N'-(2',3',4',6'-tetra-O-benzoyl-α-D-mannopyranosyl)ureido]-α-D-mannopyranoside 
• 674302-86-4 2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl isocyanide 
• 674303-05-0 2,3,4,6-tetra-O-benzoyl-β-D-mannopyranosyl isocyanide 
• 674302-85-3 C₃₅H₂₉NO₁₀ 
• 885479-57-2 C₅₄H₄₉N₃O₁₁ 
• 885479-55-0 C₅₄H₄₉N₃O₁₁ 
• 885479-59-4 1-((2S,3S,4S,5R,6R)-3,4,5-Tris-benzoyloxy-6-benzoyloxymethyl-tetrahydro-pyran-2-yl)-1H-[1,2,3]triazole-4-carboxylic acid 2-(7-isopropyl-1-methyl-azulen-4-yl)-ethyl ester 
• 885479-61-8 3-((2S,3S,4S,5R,6R)-3,4,5-Tris-benzoyloxy-6-benzoyloxymethyl-tetrahydro-pyran-2-yl)-3H-[1,2,3]triazole-4-carboxylic acid 2-(7-isopropyl-1-methyl-azulen-4-yl)-ethyl ester 
• 51970-29-7 α-D-mannopyranosyl azide 
• 33639-91-7 2,3,4,6-tetra-O-benzoyl-β-D-mannopyranosyl amine 

Relevant academic research and scientific papers

AuBr3-catalyzed azidation of per-O-acetylated and per-O-benzoylated sugars

Herein we report, for the first time, the successful anomeric azidation of per-O-acetylated and per-O-benzoylated sugars by catalytic amounts of oxophilic AuBr3 in good to excellent yields. The method is applicable to a wide range of easily accessible per-Oacetylated and per-O-benzoylated sugars. While reaction with per-O-acetylated and per-O-benzoylated monosaccharides was complete within 1-3 h at room temperature, the per-O-benzoylated disaccharides needed 2-3 h of heating at 55°C.

A novel synthesis of β-d-mannopyranosyl azide by phase transfer catalysis

A simple stereoselective synthesis of per-O-benzoyl-β-d-mannopyranosyl azide from per-O-benzoyl-α-d-mannopyranosyl bromide using phase transfer catalysis was developed. The stereochemistry at C-1 of the anomeric O-benzoylated α- and β-d-mannopyranosyl azi