65869-95-6

Basic information

• Product Name: Benzenepropanoyl chloride, a-ethyl-
• Synonyms: 2-benzyl-butyryl chloride;2-Benzyl-butyrylchlorid;2-benzylbutanoic acid;2-Benzyl-buttersaeure-chlorid
• CAS NO: 65869-95-6
• Molecular Formula: C11H13ClO
• Molecular Weight: 196.67300
• Mol File: 65869-95-6.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 124-131 °C(Press: 15 Torr)
• Density: 1.088±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Benzenepropanoyl chloride, a-ethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenepropanoyl chloride, a-ethyl-(65869-95-6)
• EPA Substance Registry System: Benzenepropanoyl chloride, a-ethyl-(65869-95-6)

Safety Data

• Hazardous Substances Data: 65869-95-6(Hazardous Substances Data)

Upstream product

• 100-44-7 benzyl chloride 
• 76154-00-2 diethyl ester of benzylethylmalonic acid 
• 56640-46-1 1-(phenylmethyl)butanoic acid 
• 607-81-8 diethyl 2-benzylmalonate 
• 4379-25-3 ethyl-benzyl-malonic acid 

Downstream Products

• 65870-05-5 2-Methyl-3-phenyl-propionic acid 2-ethyl-3H-inden-1-yl ester 
• 65870-00-0 2-(2-Benzyl-butyryl)-2-ethyl-indan-1-one 
• 137638-30-3 1,3-di(2-benzylbutanoyl)-trans-4,5-diphenylimidazolidine-2-thione 
• 137618-01-0 1,3-di(2-benzylbutanoyl)-trans-4,5-tetramethyleneimidazolidine-2-thione 
• 98090-63-2 2-benzyl-butyric acid anilide 

Relevant articles and documents

A method to prepare optically active acyclic α-benzyl ketones by thermodynamically controlled deracemization

Thermodynamically controlled deracemization of some acyclic ketones bearing a chiral center at the position α to the carbonyl group was satisfactorily achieved. Acyclic ketones with high optical purities could be isolated after treatment of the racemic ketones with base in aqueous MeOH in the presence of (-)-(2R,3R)-trans-2,3-bis(hydroxydiphenylmethyl)-1,4-dioxaspiro[5. 4]decane (1a). The efficiency of the deracemization was appreciably influenced by the ratio of H2O/MeOH used as solvent. Racemic ketones bearing a chiral center at the position α to the carbonyl group were converted into optically active ketones in the presence of TADDOL-type host molecule 1a in H2O/MeOH in suspension in basic media. Copyright