658707-42-7

Basic information

• Product Name: Phenol, 2-(diphenylphosphino)-4-methoxy-
• CAS NO: 658707-42-7
• Molecular Formula: C19H17O2P
• Molecular Weight: 308.317
• Mol File: 658707-42-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Phenol, 2-(diphenylphosphino)-4-methoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 2-(diphenylphosphino)-4-methoxy-(658707-42-7)
• EPA Substance Registry System: Phenol, 2-(diphenylphosphino)-4-methoxy-(658707-42-7)

Safety Data

• Hazardous Substances Data: 658707-42-7(Hazardous Substances Data)

Upstream product

• 120726-60-5 (2-hydroxy-5-methoxyphenyl)diphenylphosphine oxide 
• 4559-70-0 Diphenylphosphine oxide 
• 935-50-2 4,4-dimethoxycyclohexa-2,5-dienone 
• 150-76-5 4-methoxy-phenol 
• 25458-46-2 4-methoxyphenyl methoxymethyl ether 

Downstream Products

• 852574-67-5 (3-tert-butyl-5-methyl-2-oxobenzoyl)(4-methoxy-2-diphenylphosphanylphenolato)bis(trimethylphosphine)cobalt(III) 
• 857288-16-5 phenylnickel-2-diphenylphosphino-4-methoxyphenolate(O,P) (trimethylphosphine) 

Relevant articles and documents

Ph3P-mediated highly selective C(α)-P coupling of quinone monoacetals with R2P(O)H: Convenient and practical synthesis of: Ortho -phosphinyl phenols

A highly selective Ph3P-mediated C(α)-P coupling reaction of quinone monoacetals with secondary phosphine oxides is developed to provide an effective method for the synthesis of a wide array of ortho-phosphinylphenols in good to excellent yields. This protocol can be adopted for scale-up synthesis directly from cheap and abundant phenols, and the products can be easily obtained in high yields by simple filtration without the use of organic extraction or chromatography.