65877-24-9

Basic information

• Product Name: methyl 3-O-allyl-4,6-O-benzylidene-α-D-mannopyranoside
• Synonyms: methyl 3-O-allyl-4,6-O-benzylidene-α-D-mannopyranoside
• CAS NO: 65877-24-9
• Molecular Weight: 322.358
• Mol File: 65877-24-9.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: methyl 3-O-allyl-4,6-O-benzylidene-α-D-mannopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-O-allyl-4,6-O-benzylidene-α-D-mannopyranoside(65877-24-9)
• EPA Substance Registry System: methyl 3-O-allyl-4,6-O-benzylidene-α-D-mannopyranoside(65877-24-9)

Safety Data

• Hazardous Substances Data: 65877-24-9(Hazardous Substances Data)

Upstream product

• 106-95-6 allyl bromide 
• 3162-96-7 methyl-4,6-O-phenylmethylene-α-D-mannopyranoside 
• 556-56-9 allyl iodid 
• 3162-96-7 (4aS,6R,7S,8R,8aR)-6-Methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol 

Downstream Products

• 831209-96-2 methyl 2,3,4-tri-O-benzoyl-β-D-xylopyranosyl-(1->4)-2-O-acetyl-3-O-allyl-6-O-benzoyl-α-D-mannopyranoside 
• 831209-91-7 methyl 2-O-acetyl-3-O-allyl-6-O-benzoyl-α-D-mannopyranoside 
• 831210-00-5 methyl 2,3,4-tri-O-benzoyl-β-D-xylopyranosyl-(1->4)-2-O-acetyl-6-O-benzoyl-α-D-mannopyranoside 
• 831209-84-8 methyl 2-O-acetyl-3-O-allyl-4,6-O-benzylidene-α-D-mannopyranoside 
• 65817-35-8 methyl 3-O-allyl-2-O-methyl-4,6-O-benzylidene-α-D-mannopyranoside 
• 106499-04-1 methyl 3-O-allyl-2-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside 
• 186540-07-8 methyl 2-O-benzyl-4,6-O-benzylidene-3-O-(2-O-acetyl-4,6-O-benzylidene-3-O-methyl-α-D-mannopyranosyl)-α-D-mannopyranoside 
• 186539-93-5 methyl 4,6-O-benzylidene-2-O-propyl-α-D-mannopyranoside 
• 186539-89-9 methyl 4,6-O-(R)-benzylidene-2-O-ethyl-α-D-mannopyranoside 
• 65877-26-1 methyl 2-O-methyl-4,6-O-benzylidene-α-D-mannopyranoside 
• 100662-84-8 methyl α-D-mannopyranoside 2-benzyl ether 
• 15038-71-8 methyl 2-O-benzyl-(R)-4,6-O-benzylidene-α-D-mannopyranoside 
• 186539-87-7 methyl 2-O-ethyl-3-O-allyl-4,6-O-benzylidene-α-D-mannopyranoside 

Relevant articles and documents

Regioselective mono and multiple alkylation of diols and polyols catalyzed by organotin and its applications on the synthesis of value-added carbohydrate intermediates

A catalytic amount of dibutyltin dichloride was used to develop regioselective alkylation of diols and multiple alkylation of polyols. Alkyl groups, including allyl, alkynyl and long-chain alkyl groups, were successfully introduced to one or two hydroxyl

An Iron(III) Catalyst with Unusually Broad Substrate Scope in Regioselective Alkylation of Diols and Polyols

In this study, [Fe(dibm)3] (dibm=diisobutyrylmethane) is shown to have unusually broad scope as a catalyst for the selective monoalkylation of a diverse set of 1,2- and 1,3-diol-containing structures. The mechanism is proposed to proceed via a cyclic dioxolane-type intermediate, formed between the iron(III) species and two adjacent hydroxyl groups. This approach represents the first transition-metal catalysts that are able to replace stoichiometric amounts of organotin reagents in regioselective alkylation. The reactions generally lead to very high regioselectivities and high yields, on par with, or better than, previous methods used for regioselective alkylation.

Tin-mediated regioselective benzylation and allylation of polyols: Applicability of a catalytic approach under solvent-free conditions

The first catalytic version of the stannylene-mediated benzylation and allylation of polyols is reported. The methodology is based on a simple solvent-free protocol that significantly advances, in terms of both experimental ease and synthetic scope, the a