65914-22-9

Basic information

• Product Name: 1,4,6-Tri-O-acetyl-α,β-D-erythro-hex-2-enopyranose (Pseudo-C-glucal triacetate)
• Synonyms: 1,4,6-Tri-O-acetyl-α,β-D-erythro-hex-2-enopyranose (Pseudo-C-glucal triacetate)
• CAS NO: 65914-22-9
• Molecular Weight: 272.255
• Mol File: 65914-22-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,4,6-Tri-O-acetyl-α,β-D-erythro-hex-2-enopyranose (Pseudo-C-glucal triacetate)(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4,6-Tri-O-acetyl-α,β-D-erythro-hex-2-enopyranose (Pseudo-C-glucal triacetate)(65914-22-9)
• EPA Substance Registry System: 1,4,6-Tri-O-acetyl-α,β-D-erythro-hex-2-enopyranose (Pseudo-C-glucal triacetate)(65914-22-9)

Safety Data

• Hazardous Substances Data: 65914-22-9(Hazardous Substances Data)

Upstream product

• 52485-06-0 3,4,6-tri-O-acetyl-D-glucal 

Downstream Products

• 3323-72-6 ethyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythrohex-2-enopyranoside 
• 23339-26-6 isopropyl 2,3-dideoxy-α-D-erythro-hex-2-enopyranoside 
• 138639-03-9 11,13-Di-O-acetyl-8,12-anhydro-3,5-di-O-benzyl-6,7-dideoxy-1,2-O-isopropylidene-6-C-methylene-D-ribo-α-D-gluco-trideca-9-eno-1,4-furanose 
• 138639-02-8 Methyl 11,13-di-O-acetyl-8,12-anhydro-2,3,4-tri-O-benzyl-6,7-dideoxy-6-C-methylene-D-ribo-α-D-gluco-trideca-9-eno-1,5-pyranoside 

Relevant articles and documents

Novel C-3 Epimerization of Glycals by Metal Chlorides

Treatment of tri-O-acetyl-D-glycals, e.g., tri-O-acetyl-D-glucal, tri-O-acetyl-D-allal and tri-O-acetyl-D-galactal, with metal chlorides in acetic anhydride afforded the C-3 epimer of the glycal triacetate with pseudo-glycal triacetate and unreacted glycal triacetate as an equilibrium mixture.The C-3 epimer of the glycal was readily separated from the reaction mixture using preparative HPLC.