138639-02-8

Basic information

• Product Name: Methyl 11,13-di-O-acetyl-8,12-anhydro-2,3,4-tri-O-benzyl-6,7-dideoxy-6-C-methylene-D-ribo-α-D-gluco-trideca-9-eno-1,5-pyranoside
• CAS NO: 138639-02-8
• Molecular Weight: 686.799
• Mol File: 138639-02-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Methyl 11,13-di-O-acetyl-8,12-anhydro-2,3,4-tri-O-benzyl-6,7-dideoxy-6-C-methylene-D-ribo-α-D-gluco-trideca-9-eno-1,5-pyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 11,13-di-O-acetyl-8,12-anhydro-2,3,4-tri-O-benzyl-6,7-dideoxy-6-C-methylene-D-ribo-α-D-gluco-trideca-9-eno-1,5-pyranoside(138639-02-8)
• EPA Substance Registry System: Methyl 11,13-di-O-acetyl-8,12-anhydro-2,3,4-tri-O-benzyl-6,7-dideoxy-6-C-methylene-D-ribo-α-D-gluco-trideca-9-eno-1,5-pyranoside(138639-02-8)

Safety Data

• Hazardous Substances Data: 138639-02-8(Hazardous Substances Data)

Upstream product

• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 
• 138638-92-3 Methyl 2,3,4-tri-O-benzyl-6-bis-C-<(trimethylsilyl)methyl>-α-D-glucopyranoside 
• 55610-71-4 methyl (methyl-2,3,4-tri-O-benzyl-α-D-glucopyranosid)uronate 
• 120444-48-6 (2S,3S,4S,5R,6S)-3,4,5-tris(benzyloxy)-6-methoxytetrahydro-2H-pyran-2-carboxylic acid 
• 65914-22-9 1,4,6-Tri-O-acetyl-α,β-D-erythro-hex-2-enopyranose (Pseudo-C-glucal triacetate) 
• 138638-93-4 Methyl 2,3,4-tri-O-benzyl-6,7-dideoxy-6-C-methylene-7-C-trimethylsilyl-α-D-gluco-hepto-1,5-pyranoside 

Relevant articles and documents

A one-step C-linked disaccharide synthesis from carbohydrate allylsilanes and tri-O-acetyl-D-glucal

The reaction of protected glucuronic esters 2 and 7, as well as D-glucuronolactone derivative 11, with (trimethylsilyl)methylmagnesium chloride in ether led to the corresponding stable bis-silyl adducts 3, 8, and 12, respectively. In Peterson-type reactio