65914-68-3

Upstream product

• 5792-35-8 2,3-dihydroxy-1-phenylpropan-1-one 
• 7732-18-5 water 
• 64-17-5 ethanol 
• 104-54-1 3-Phenylpropenol 
• 40641-81-4 trans-2,3-epoxy-3-phenylpropan-1-ol 
• 110379-48-1 (R)-(R)-[1,3]Dioxolan-4-yl-phenyl-methanol 
• 21915-53-7 cis-2,3-epoxy-3-phenyl-1-propanol 
• 110379-53-8 [1,3]Dioxolan-4-yl-phenyl-methanone 
• 110379-48-1 (R)-(S)-[1,3]Dioxolan-4-yl-phenyl-methanol 
• 103-26-4 Methyl cinnamate 
• 81691-59-0 (2RS,3RS)-2,3-dihydroxy-3-phenyl-propionic acid methyl ester 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 50555-04-9 cinnamyl benzoate 
• 162599-28-2 (1S:2R)-1.2.3-tribenzoyloxy-1-phenyl-propane 

Downstream Products

• 859185-40-3 2-(4-nitro-phenyl)-4-phenyl-[1,3]dioxan-5-ol 
• 859935-23-2 5-methoxy-2-(4-nitro-phenyl)-4-phenyl-[1,3]dioxane 
• 16354-94-2 C₃₀H₂₄O₆ 
• 26151-12-2 (2,2-dimethyl-[1,3]dioxolan-4-yl)-phenyl-methanol 
• 859813-98-2 (2,2-dimethyl-5-phenyl-[1,3]dioxolan-4-yl)-methanol 
• 16354-94-2 (1RS,2RS)-1,2,3-tris-benzoyloxy-1-phenyl-propane 

Relevant academic research and scientific papers

Molybdenum-Catalyzed Hydroxyl-Directed Anti-Dihydroxylation of Allylic and Homoallylic Alcohols

A catalytic hydroxyl-directed anti-dihydroxylation of allylic and homoallylic alcohols has been developed. This operationally simple method was successfully applied to the direct anti-monodihydroxylation of allylic alcohols containing at least one distal olefinic unit. Under the catalysis of commercially available MoO2(acac)2, an array of hydroxylated dienes were successfully converted into various 1,2,3-triols using hydrogen peroxide as an environmentally benign oxidant under aerobic conditions, notably, in complete regioselectivities and in the most cases in diastereospecific pathway.

CYCLOFUNCTIONALISATION OF EPOXYALCOHOL DERIVATIVES. 2. STEREO- AND REGIOSPECIFIC CONVERSION TO 1,3-DIOXOLANES

2,3-Epoxyalcohols react with paraformaldehyde and either cesium carbonate or potassium carbonate/phase-transfer catalyst in polar, aprotic solvents to give excellent yields of 4-(1-hydroxyalkyl)-1,3-dioxolanes, with inversion at C-2.