65930-08-7

Upstream product

• 90-43-7 2-Phenylphenol 
• 79-41-4 poly(methacrylic acid) 
• 920-46-7 Methacryloyl chloride 

Relevant academic research and scientific papers

Preparation and Enzymatic Hydrolysis of Polymers Anchoring Biphenyl-2-ol

Polymers anchoring fungicidal biphenyl-2-ol(BPOL) were prepared by the polymerization and copolymerization of 2-biphenylyl methacrylate(BPMA) with various comonomers such as styrene, vinyl acetate, 2-hydroxyethyl methacrylate, N-methacryloylglycine, and N-methacryloyl-DL-alanine.The reactivity ratios of BPMA with the comonomers were evaluated.The α-chymotrypsin-catalyzed hydrolysis of the polymers was also studied.The release of BPOL from the polymers was represented by means of the Michaelis constant Km and the catalytic-rate constant kcat.The BPMA homopolymer gave higher Km and kcat values than the copolymers, and the copoly mers with a higher content of substrate units underwent cleavage more readily.It was found that the hydrolysis of the polymeric substrates is affected by the structure and character of the comonomer rather than the arrangement order of the repeating monomer units in the polymer sequence.

METHOD FOR PRODUCING (METH) ACRYLATE

PROBLEM TO BE SOLVED: To provide a production method for obtaining (meth) acrylate in high yields, by preventing a large amount of waste from produced from by-products, like the conventional art. SOLUTION: A method for producing (meth) acrylate includes the reaction between a compound represented by the following formula (I) and an aryl alcohol. Preferably, the reaction occurs in the presence of a catalyst of at least one metal compound selected from first Group metal compounds and second Group metal compounds. SELECTED DRAWING: None COPYRIGHT: (C)2019,JPOandINPIT

CARBOXYLIC ACID ESTER PRODUCTION METHOD

Provided is a production method whereby corresponding carboxylic acid esters can be obtained from a variety of carboxylic acids at a high yield, even under conditions using a simple reaction operation and little catalyst and even if the amount of substrate used is theoretical. A production method for carboxylic acid ester, whereby a prescribed diester dicarbonate, carboxylic acid, and alcohol are reacted in the presence of at least one type of magnesium compound and at least one type of alkali metal compound.

METHOD FOR PRODUCING CARBOXYLIC ACID ANHYDRIDE AND METHOD FOR PRODUCING CARBOXYLIC ACID ESTER

Provided is a production method whereby corresponding carboxylic acid anhydrides and carboxylic acid esters can be obtained at high yield from various carboxylic acids even without a solvent and near room temperature. A method for producing a carboxylic acid anhydride represented by formula (II), the method comprising reacting a compound represented by formula (I) and a carboxylic acid in the presence of a Group II metal compound having an ionic ligand containing an oxygen atom. A method for producing a carboxylic acid ester, the method comprising reacting a carboxylic acid anhydride produced by the aforementioned method and an alcohol. In formula (I), R1 represents a C1-20 hydrocarbon group. In formula (II), R2 represents a C1-20 hydrocarbon group.