65934-71-6

Basic information

• Product Name: Benzenamine, N-(1-methylethyl)-3-(trifluoromethyl)-
• CAS NO: 65934-71-6
• Molecular Formula: C10H12F3N
• Molecular Weight: 203.207
• Mol File: 65934-71-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-(1-methylethyl)-3-(trifluoromethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-(1-methylethyl)-3-(trifluoromethyl)-(65934-71-6)
• EPA Substance Registry System: Benzenamine, N-(1-methylethyl)-3-(trifluoromethyl)-(65934-71-6)

Safety Data

• Hazardous Substances Data: 65934-71-6(Hazardous Substances Data)

Upstream product

• 98-16-8 3-trifluoromethylaniline 
• 67-64-1 acetone 
• 108-18-9 diisopropylamine 
• 588-00-1 1,2-bis(3-(trifluoromethyl)phenyl)diazene 
• 98-46-4 3-trifluoromethylnitrobenzene 
• 351-19-9 1,2-bis(3-(trifluoromethyl)phenyl)hydrazine 

Downstream Products

• 1350911-15-7 vinyl 3-(trifluoromethyl)phenylisopropylcarbamate 
• 1350911-21-5 1-iodovinyl 3-(trifluoromethyl)phenylisopropylcarbamate 
• 1350911-47-5 5,5-dimethylhex-1-en-3-yn-2-yl 3-(trifluoromethyl)phenylisopropylcarbamate 
• 1350912-02-5 4-(3-(trifluoromethyl)phenyl)-2,7,7-trimethyloct-5-yn-4-ol 
• 1350912-03-6 4-(3-(trifluoroethyl)phenyl)-2,2,7,7-tetramethyloct-5-yn-4-ol 

Relevant articles and documents

Tertiary alcohols by tandem β-carbolithiation and N→C aryl migration in enol carbamates

Enol carbamates (O-vinylcarbamates) derived from aromatic or α,β-unsaturated compounds and bearing an N-aryl substituent undergo carbolithiation by nucleophilic attack at the (nominally nucleophilic) β position of the enol double bond. The resulting carbamate-stabilized allylic, propargylic, or benzylic organolithium rearranges with N→C migration of the N-aryl substituent, creating a quaternary carbon α to O. The products may be readily hydrolyzed to yield multiply branched tertiary alcohols in a one-pot tandem reaction, effectively a polarity-reversed nucleophilic β-alkylation-electrophilic α-arylation of an enol equivalent.

Ultrasonically activated reduction of substituted nitrobenzenes to corresponding N-arylhydroxylamines

Arylhydroxylamines can be obtained by reduction of the corresponding nitroaromatic compounds. We report here an efficient preparation of arylhydroxylamines by a controlled reduction of nitro compounds using zinc metal and ammonium chloride under ultrasonic activation in very short reaction times.