65977-70-0

Basic information

• Product Name: 1-(tert-butyl)-4-(2-methylprop-1-en-1-yl)benzene
• Synonyms: 1-(tert-butyl)-4-(2-methylprop-1-en-1-yl)benzene
• CAS NO: 65977-70-0
• Molecular Weight: 188.313
• Mol File: 65977-70-0.mol

Chemical Properties

• CAS DataBase Reference: 1-(tert-butyl)-4-(2-methylprop-1-en-1-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(tert-butyl)-4-(2-methylprop-1-en-1-yl)benzene(65977-70-0)
• EPA Substance Registry System: 1-(tert-butyl)-4-(2-methylprop-1-en-1-yl)benzene(65977-70-0)

Safety Data

• Hazardous Substances Data: 65977-70-0(Hazardous Substances Data)

Upstream product

• 939-97-9 4-tert-Butylbenzaldehyde 
• 16666-80-1 triphenylphosphonio-1-methylethanide 
• 1530-33-2 isopropyltriphenylphosphonium bromide 
• 60-35-5 acetamide 
• 86439-83-0 DL-3,4-Bis(4-tert-butylphenyl)-2,2,5,5-tetramethylhexan 
• 345948-38-1 meso-3,4-Bis(4-tert-butylphenyl)-2,2,5,5-tetramethylhexan 

Downstream Products

• 73566-44-6 1-(tert-butyl)-4-(2-methylallyl)benzene 
• 807266-58-6 1-(4-(tert-butyl)phenyl)-2-methylpropan-2-amine 

Relevant articles and documents

Regioselective differentiation of vicinal methylene C-H bonds enabled by silver-catalysed nitrene transfer

Silver-catalyzed nitrene insertion enables the formation of benzosultams in good yield and with regioselectivity complementary to other transition metal nitrene-transfer catalysts. Preferential formation of six-membered benzosultam rings predominates for alkyl-substituted benzenesulphonamide precursors. Ligand-controlled tunability is also achieved for benzenesulphonamides with γ-branched alkyl substituents. Mechanistic probes suggest that the reaction pathway differs depending on whether a α (benzylic) or β (homobenzylic) C-H bond undergoes amidation, as well as the catalyst identity.

Silver-Catalysed Hydroarylation of Highly Substituted Styrenes

Hydroarylation is an effective strategy to rapidly increase the complexity of organic structures by transforming flat alkene moieties into three-dimensional frameworks. Many strategies have already been developed to achieve the hydroarylation of styrenes,

Thermolabile Hydrocarbons, XVIII. 1-Substituted Neopentyl radicals and their Dimers

Five 3,4-diaryl-2,2,5,5-tetramethylhexanes 1a - e were prepared as pure meso- and DL-isomers.According to the NMR spectra, x-ray analyses for meso- and DL-1e (with an (FB)2E conformation as energy minimum for DL-1e), and force field calculations the diastereomers have distinctly different minimum energy conformations, rotational potentials, and strain enthalpies.Also the activation parameters for the thermal dissociation into 1-arylneopentyl radicals 2 are typically differing.From an entropy discussion it is concluded that sandwich-like diastereomeric radical complexes are formed in these reactions as first intermediates.Their tightness influences ΔS%.The recombinations of the radicals 2 likewise take place stereoselectively.Their substituent effects on the selectivity can also be understood by primary formation of diastereomeric complexes of radical pairs.