66007-17-8

Basic information

• Product Name: (S)-14-Methyl-(Z)-8-hexadecenal
• CAS NO: 66007-17-8
• Molecular Weight: 252.44
• Mol File: 66007-17-8.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: (S)-14-Methyl-(Z)-8-hexadecenal(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-14-Methyl-(Z)-8-hexadecenal(66007-17-8)
• EPA Substance Registry System: (S)-14-Methyl-(Z)-8-hexadecenal(66007-17-8)

Safety Data

• Hazardous Substances Data: 66007-17-8(Hazardous Substances Data)

Upstream product

• 37610-80-3 1,3-dioxolan-2-ylethylmagnesium bromide 
• 114905-16-7 Acetic acid (Z)-9-[1,3]dioxolan-2-yl-non-2-enyl ester 
• 37179-47-8 (S)-6-methyloctanal 
• 70200-32-7 (S)-4-Methylhexyl p-toluenesulfonate 
• 66007-18-9 (S,E)-(+)-14-methyl-8-hexadecen-1-ol 
• 66007-19-0 (S,E)-(+)-14-methyl-8-hexadecenal (trogodermal) 
• 629-30-1 1,7-heptandiol 
• 10160-24-4 7-bromoheptyl alcohol 
• 10160-25-5 7-bromo-1-(2-tetrahydropyranyloxy)heptane 
• 1448019-20-2 ethyl (R,E)-8-(benzyloxy)-6-methyloct-2-enoate 
• 83541-13-3 (R)-(+)-6-(benzyloxy)-4-methylhexanal 
• 1448019-22-4 (R)-8-(benzyloxy)-6-methyloctanal 
• 1448019-31-5 (3R)-3-methyl-16-(tetrahydro-2H-pyran-2-yloxy)hexadec-8-yn-1-ol 
• 1448019-30-4 2-[(R)-16-(benzyloxy)-14-methylhexadec-8-ynyloxy]tetrahydro-2H-pyran 

Relevant articles and documents

A practical total synthesis of both e - And Z -isomers of optically pure (S)-14-methylhexadec-8-enal (Trogodermal)

The total synthesis of both E- and Z-isomers of optically pure (S)-14-methylhexadec-8-enal (trogodermal) is described. Key steps involved Corey-Fuchs reaction, zipper isomerization, and different hydrogenation conditions for cis- and trans-isomers. Georg

GLYCALS IN STEREOCHEMICAL SYNTHESIS SYNTHESIS OF (14R,8Z)-TROGODERMAL AND ITS (14S,8Z)-ENANTIOMER FROM DI-O-BENZOYL-D- AND -L-ARABINALS

Enantiomerically pure (14R)-14-methylhexadeca-8Z-enal (cis-trogodermal) - the aggregation pheromone of the khapra beetle (Trogoderma) - and its (14S,8Z)-enantiomer has been effected from di-O-benzoyl-D- and -L-arabinals.

Pheromones, 67. - Synthesis of the Enantiomers of (Z)-14-Methyl-8-hexadecenal , the Pheromone of Some Trogoderma Species (Coleoptera: Dermestidae)

The separation of diastereomeric phenylglycinolamides of 2-methylbutyric acid by means of MPLC yields the pure enantiomers of the acid, from which (R,Z)- and (S,Z)-14-methyl-8-hexadecenal (1) (trogodermal) can be obtained.