66008-39-7Relevant academic research and scientific papers
Stereochemistry of Nucleophilic Addition Reactions. 10. Preparation of 2-C-Diacetylmethyl and 2-C-Acetylmethyl Derivatives with the Altro, Gluco, and Manno Configuration from Methyl 4,6-O-Benzylidene-2,3-dideoxy-3-nitro-α-D-erythro-hex-2-enopyranoside
Sakakibara, Tohru,Seta, Akinori,Tachimori, Yoshifusa,Sudoh, Rokuro
, p. 2322 - 2326 (2007/10/02)
Reaction of the title compound with acetylacetone in the presence of a catalytic amount of sodium hydroxide afforded the 2-C-diacylmethyl and 2-C-acetylmethyl derivatives having the altro, gluco, and manno configurations.The 2-C-diacetylmethyl derivative with the altro configuration exceptionally exists in a skew boat form.The product ratio depends on solvent and amount of THF.
