66031-49-0Relevant articles and documents
EIGHT ALIPHATIC ALDEHYDES FROM CIRSIUM DIPSACOLEPIS AND THEIR STEREOSELECTIVE SYNTHESIS
Takano, Satoshi,Kawaminami, Shunro
, p. 435 - 438 (1987)
Two new and six known aliphatic aldehydes have been isolated from the roots of Cirsium dipsacolepis, viz. 7-octenal, (2E)-2,8-nonadienal, (2E)-2,9-decadienal, (2E)-2,10-undecadienal, (2E,4E)-2,4,10-undecatrienal, (2E,4E)-2,4,11-dodecatrienal, (2Z,4Z)-2,4,11-dodecatrienal and (2E,4Z)-2,4,11-dodecatrienal.The aldehydes were identified and synthesized stereoselectively from alkene-α,ο-diynes. Key word Index-- Cirsium dipsacolepis; Compositae; roots; unsaturated aliphatic aldehydes; aplotaxene; cyperene; synthesis.
Selective iron-catalyzed transfer hydrogenation of terminal alkynes
Wienhoefer, Gerrit,Westerhaus, Felix A.,Jagadeesh, Rajenahally V.,Junge, Kathrin,Junge, Henrik,Beller, Matthias
supporting information; experimental part, p. 4827 - 4829 (2012/06/04)
A novel iron-catalyzed transfer hydrogenation of alkynes to the corresponding alkenes applying formic acid as a hydrogen donor is reported. An in situ combination of Fe(BF4)2·6H2O and tetraphos allows for highly selective hydrogenation of a broad range of aromatic and aliphatic alkynes tolerating different functional groups.
Experimental determination of the activation parameters and stereoselectivities of the intramolecular Diels-Alder reactions of 1,3,8-nonatriene, 1,3,9-decatriene, and 1,3,10-undecatriene and transition state modeling with the Monte Carlo-Jumping between Wells/molecular dynamics method
Diedrich, Matthias K.,Kl?rner, Frank-Gerrit,Beno, Brett R.,Houk,Senderowitz, Hanoch,Still, W. Clark
, p. 10255 - 10259 (2007/10/03)
Experimental activation parameters for the intramolecular Diels-Alder reactions of 1,3,8-nonatriene, 1,3,9-decatriene, and 1,3,10-undecatriene have been measured, and the Monte Carlo-Jumping between Wells/Stochastic Dynamics [MC(JBW)/SD] method, which gives relative free energies of activation, was tested as a means to predict stereoselectivities. The predictions are compared to experimental results, and to predictions from quantum and molecular mechanics methods.