6605-37-4Relevant academic research and scientific papers
Effective and chemoselective glycosylations using 2,3-unsaturated sugars
Kusumi, Shunichi,Sasaki, Kaname,Wang, Sainan,Watanabe, Tatsuya,Takahashi, Daisuke,Toshima, Kazunobu
experimental part, p. 3164 - 3178 (2010/08/21)
Glycosyl donors containing a double bond between C2 and C3 were designed by mimicking the reaction mechanism of lysozyme-initiated hydrolysis of mucopolysaccharides. It was found that, under various glycosylation conditions, the reactivities of 2,3-unsatu
An efficient glycosidation method using 2,3-unsaturated glycosyl donors
Sasaki, Kaname,Matsumura, Shuichi,Toshima, Kazunobu
, p. 9039 - 9043 (2007/10/03)
A novel class of 'armed' glycosyl donors containing a double bond at the C-2 position was designed by mimicking the mechanism of lysozyme-initiated hydrolysis. These donors were used to achieve chemoselective glycosidation of hex-2-enopyranosyl acetate an
TRANSACETALISATION PROCESS
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Page/Page column 50, (2010/02/13)
The invention relates to the resolution of racemic mixtures, and in particular to the separation of enantiomers of chiral alcohols utilising recyclable chiral auxiliaries. The present invention also relates to a process for preparing these recyclable chiral auxiliaries using an enantiomerically pure alcohol.
