6611-92-3

Basic information

• Product Name: 1,3-Dioxolane, 2-methyl-2-(3-methyl-2-butenyl)- (7CI,9CI)
• Synonyms: 1,3-Dioxolane, 2-methyl-2-(3-methyl-2-butenyl)- (7CI,9CI)
• CAS NO: 6611-92-3
• Molecular Formula: C9H16O2
• Molecular Weight: 156.22
• Mol File: 6611-92-3.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1,3-Dioxolane, 2-methyl-2-(3-methyl-2-butenyl)- (7CI,9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Dioxolane, 2-methyl-2-(3-methyl-2-butenyl)- (7CI,9CI)(6611-92-3)
• EPA Substance Registry System: 1,3-Dioxolane, 2-methyl-2-(3-methyl-2-butenyl)- (7CI,9CI)(6611-92-3)

Safety Data

• Hazardous Substances Data: 6611-92-3(Hazardous Substances Data)

Usage

Appearance

Colorless liquid

Odor

Faint, pleasant

Physical state

Liquid

Usage

a. Solvent in various industrial applications
b. Reagent in organic synthesis
c. Production of pharmaceuticals
d. Production of flavors and fragrances
e. Production of other chemical compounds

Stability

Relatively stable under normal conditions

Reactivity

a. May react violently with oxidizing agents
b. May react violently with strong acids
c. May react violently with strong bases

Safety precautions

Handle and store with caution due to potential hazardous properties

Upstream product

• 1669-43-8 (E)-4-isopropylbut-3-en-2-one 
• 107-21-1 ethylene glycol 
• 28332-44-7 5-methylhex-4-en-2-one 

Downstream Products

• 18871-63-1 3,3-ethylenedioxybutanal 

Relevant articles and documents

SYNTHESE D'ACETOACETALDEHYDES MONO- ET DI-SUBSTITUES PAR DES CHAINES FONCTIONNALISEES

These synthons, which are useful in the synthesis of indole alkaloids, were prepared through alkylation of enone 4 and further ozonolysis, after eventual protection in the form of dioxolane derivatives.

Synthesis of Chloromethylvinylcyclopropanecarboxylic Acid Derivatives

The compound 3-(2-chloro-1-propenyl)-2,2-dimethylcyclopropanecarboxylate, which is a hybrid structure of naturally occuring chrysanthemic acid and dichlorovinylcyclopropanecarboxylate, was synthesized from several intermediates: (i) 5-methyl-4-hexen-2-one ethylene ketal (8), (ii) 2-methyl-5,5-dichloro-2-hexene (24), (iii) 5-methyl-2-chloro-2,4-hexadiene (27), (iv) ethyl 4,6-dichloro-3,3-dimethyl-5-heptenoate (35).

BASENINDUZIERTE RINGOEFFNUNG VON 1,3-DIOXOLANEN: EIN NEUER WEG ZU DIENOLETHERN

Cyclic acetals of β,γ-unsaturated carbonyl compounds may be deprotonated by NaH/DMSO.The resulting anions are unstable and give ring opening reactions to dienol ethers.