66147-00-0Relevant academic research and scientific papers
Ironcyclopentadienyl mediated 2-alkyl-2-arylphenylsulphonylacetonitrile synthesis
Abd-El-Aziz, Alaa S.,Denus, Christine R. de,Hutton, Harold M.
, p. 289 - 295 (2007/10/02)
A unique route to the synthesis of 2-alkyl-2-arylphenylsulphonylacetonitriles via the nucleophilic aromatic substitution (SNAr) of chloroarene cyclopentadienyliron complexes with 2-alkyl phenylsulphonylacetonitriles has been investigated.Reacti
Carbon-Carbon Bond Formation with New Mitsunobu Reagents
Tsunoda, Tetsuto,Nagaku, Miwa,Nagino, Chisato,Kawamura, Yumi,Ozaki, Fumie,et al.
, p. 2531 - 2534 (2007/10/02)
The efficiency of three azodicarboxylic acid derivatives and a stabilized phosphorane in the Mitsunobu type C-C bond formation was compared utilizing the reactions of three nucleophiles of different pKa's and several alcohols of different structure types.The study established the characteristics of each reagent.The synthesis of two insect pheromone analogs was accomplished effectively using these homologation reactions.
