66216-84-0Relevant articles and documents
Barium and titanium dithiocarbamates as precursors for colloidal nanocrystals of emerging optoelectronic materials
Creutz, Sidney E.,Donnadieu, Bruno,Ingram, Nicole E.,Jordan, Brian J.
supporting information, p. 15978 - 15982 (2021/11/27)
The synthesis and structures of N,N-dialkyldithiocarbamate complexes of barium are reported; the compounds crystallize as one-dimensional coordination polymers. In combination with a titanium dithiocarbamate precursor, the compounds are demonstrated as competent single-source precursors for the solution-based preparation of colloidal BaTiS3 nanorods. This journal is
Glycosyl dithiocarbamates: β-selective couplings without auxiliary groups
Padungros, Panuwat,Alberch, Laura,Wei, Alexander
, p. 2611 - 2624 (2014/04/17)
In this article, we evaluate glycosyl dithiocarbamates (DTCs) with unprotected C2 hydroxyls as donors in β-linked oligosaccharide synthesis. We report a mild, one-pot conversion of glycals into β-glycosyl DTCs via DMDO oxidation with subsequent ring opening by DTC salts, which can be generated in situ from secondary amines and CS2. Glycosyl DTCs are readily activated with Cu(I) or Cu(II) triflate at low temperatures and are amenable to reiterative synthesis strategies, as demonstrated by the efficient construction of a tri-β-1,6-linked tetrasaccharide. Glycosyl DTC couplings are highly β-selective despite the absence of a preexisting C2 auxiliary group. We provide evidence that the directing effect is mediated by the C2 hydroxyl itself via the putative formation of a cis-fused bicyclic intermediate.
Dibenzylammonium and Sodium Dibenzyldithiocarbamates as Precipitants for Preconcentration of Trace Elements in Water for Analysis by Energy Dispersive X-ray Fluorescence
Moore, Robert V.
, p. 895 - 897 (2007/10/02)
Precipitation with combined dibenzylammonium dibenzyldithiocarbamate and sodium dibenzyldithiocarbamate at pH 5.0 can be used to separate 22 trace elements from water.Membrane filtration of the precipitate yielded a thin sample, suitable for analysis by energy dispersive X-ray fluorescence spectrometry.Alkalis, alkaline earths, lanthanides, and halides were not precipitated, permitting a clean separation of trace elements from the macro constituents of drinking water and drinking water supplies.Methods are given for preparation of reagents of higher purity than previo usly described.
