66217-92-3

Basic information

• Product Name: Morpholine, 4-(1-phenyl-1-propenyl)-, (Z)-
• CAS NO: 66217-92-3
• Molecular Formula: C13H17NO
• Molecular Weight: 203.284
• Mol File: 66217-92-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Morpholine, 4-(1-phenyl-1-propenyl)-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Morpholine, 4-(1-phenyl-1-propenyl)-, (Z)-(66217-92-3)
• EPA Substance Registry System: Morpholine, 4-(1-phenyl-1-propenyl)-, (Z)-(66217-92-3)

Safety Data

• Hazardous Substances Data: 66217-92-3(Hazardous Substances Data)

Upstream product

• 110-91-8 morpholine 
• 93-55-0 1-phenyl-propan-1-one 
• 673-32-5 1-Phenylprop-1-yne 

Downstream Products

• 47074-06-6 2-Methyl-1,5-diphenyl-1,5-pentanedione 
• 142597-54-4 2-methyl-1-phenylhexane-1,5-dione 
• 21120-36-5 1-fluoroethyl phenyl ketone 
• 703-17-3 1-phenyl-2,2-difluoropropan-1-one 
• 25888-24-8 1-Phenyl-2-propanon-(1) 
• 196702-55-3 Thioacetic acid S-(2-methyl-3-oxo-3-phenyl-propyl) ester 
• 40394-84-1 3-Methyl-4-oxo-4-phenyl-butansaeure-ethylester 
• 5650-40-8 2-hydroxypropiophenone 
• 891866-07-2 1-(2-chlorophenyl)-4-methyl-5-phenyl-1H-pyrazole-3-carboxylic acid ethyl ester 
• 1284281-24-8 ethyl 1-(2-fluorophenyl)-4-methyl-5-phenyl-1H-pyrazole-3-carboxylate 
• 1284281-28-2 ethyl 1-(4-bromophenyl)-4-methyl-5-phenyl-1H-pyrazole-3-carboxylate 
• 1284281-26-0 ethyl 1-(3-bromophenyl)-4-methyl-5-phenyl-1H-pyrazole-3-carboxylate 
• 1284281-32-8 ethyl 1-(2-phenylphenyl)-4-methyl-5-phenyl-1H-pyrazole-3-carboxylate 
• 1284281-30-6 ethyl 1-(2-iodophenyl)-4-methyl-5-phenyl-1H-pyrazole-3-carboxylate 

Relevant articles and documents

Achieving Aliphatic Amine Addition to Arylalkynes via the Lewis Acid Assisted Triazole-Gold (TA-Au) Catalyst System

Transition metal catalyzed intermolecular hydroamination of the arylalkynes with aliphatic amine is generally problematic due to the good coordination between amine and metal cation. With the combination of 1,2,3-triazole coordinated gold(I) catalyst (TA-Au) and Zn(OTf)2 cocatalyst, this challenging transformation was achieved with good to excellent yields and regioselectivity. Compared to previously reported methods, this approach offered an alternative catalyst system to achieve this fundamental chemical transformation with high efficiency and practical conditions.

Reactions of enamines with selectfluor: A straightforward route to difluorinated carbonyl compounds

Reactions of enamines, preformed from β-dicarbonyl and monocarbonyl compounds, with Selectfluor (1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2] octane bis(tetrafluoroborate) under mild conditions (triethylamine (TEA) or molecular sieves) easily led to the corresponding difluorinated carbonyl compounds in high yields.

Studies on the Oxidation of Enamines with Molecular Oxygen. III Oxidation of Some Amino Styrenes

In the oxidation of the amino styrenes 1a - 1j only products of the oxidative attack at the C=C double bond and hydrolysis products are obtained.Aprotic dipolar solvents and the addition of molecular sieve 5A promote the oxygen uptake.The addition of hydroquinone to the oxidation system does not influence the rate of oxygen absorption or the yields of the oxidation products.