66221-50-9Relevant academic research and scientific papers
Asymmetric synthesis of both enantiomers of α-methyl-α-methoxyphenylacetic acid from l-(+)-tartaric acid: formal enantioselective synthesis of insect pheromone (-)-frontalin
Prasad, Kavirayani R.,Chandrakumar, Appayee,Anbarasan, Pazhamalai
, p. 1979 - 1984 (2007/10/03)
Both antipodes of α-methyl-α-methoxyarylacetic acid derivatives were prepared from a common chiralpool precursor l-(+)-tartaric acid. The key step involves the addition of Grignard reagents to 1,4-diketones derived from tartaric acid. The utility of this
A new preparative route to chiral 2,3-epoxy-1,4-butanediols
Aoyama,Urabe,Sato
, p. 6731 - 6734 (2007/10/02)
Chiral 2,3-epoxy-1,4-butanediols including those have a quaternary carbon center have been prepared from optically active 3-cyano-2,3-epoxy-1-propanol.
