912646-23-2Relevant academic research and scientific papers
Asymmetric synthesis of both enantiomers of α-methyl-α-methoxyphenylacetic acid from l-(+)-tartaric acid: formal enantioselective synthesis of insect pheromone (-)-frontalin
Prasad, Kavirayani R.,Chandrakumar, Appayee,Anbarasan, Pazhamalai
, p. 1979 - 1984 (2007/10/03)
Both antipodes of α-methyl-α-methoxyarylacetic acid derivatives were prepared from a common chiralpool precursor l-(+)-tartaric acid. The key step involves the addition of Grignard reagents to 1,4-diketones derived from tartaric acid. The utility of this
