66277-23-4Relevant academic research and scientific papers
BIOSYNTHESIS OF β-METHYLENENORVALINE (2-AMINO-3-ETHYL-3-BUTENOIC ACID) IN PHILADELPHUS
Crout, David H. G.,Piper, Ian M.,Sehgal, Charanjit K.
, p. 1399 - 1402 (1987)
Key Word Index - Philadelphus; Saxifragaceae; β-methylenenorvaline; 2-amino-3-ethyl-3-butenoic acid; biosynthesis; synthesis. β-Methylenenorvaline (2-amino-3-ethyl-3-butenoic acid) was synthesized.The specific incorporation of isoleucine (as a mixture of L-isoleucine and D-alloisoleucine) into β-methylenenorvaline in Philadelphus cv Belle Etoile was demonstrated.
Ueber einen neuartigen synthetischen Zugang zu β,γ-ungesaettigten α-Aminocarbonsaeuren
Heinzer, Franz,Bellus, Daniel
, p. 2279 - 2297 (2007/10/02)
A versatile new synthetic pathway for the preparation of β,γ-unsaturated α-amino acids (1) is presented.Cu(I)-catalyzed addition of ethyl isocyanoacetate (2) to α-chloro carbonyl compounds (3) gives 5-chloroalkyl-2-oxazolin-4-carboxylates (4) in high yiel
