66312-68-3Relevant academic research and scientific papers
Nazarov reactions of vinyl cyclopropylamines: An approach to the imino-nazarov problem
Bonderoff, Sara A.,Grant, Tina N.,West,Tremblay, Martin
supporting information, p. 2888 - 2891 (2013/07/26)
Dichlorocyclopropanation of 2-amino-1,3-dienes affords 1-alkenyl-1-amino-2, 2-dichlorocyclopropanes which undergo silver-assisted 2-π electrocyclic opening to furnish 3-aminopentadienyl cations. Nazarov-type cyclization of these intermediates leads to cyclopentenone iminium salts, which provide allylic amines upon reduction. This process, the imino version of the traditional Nazarov reaction, can also be combined with an interrupted Nazarov domino process to give polycyclic amines.
Catalytic Aminomercuration Reactions of 3-Alken-1-ynes: An Improved Method for the Synthesis of 2-Amino-1,3-butadienes and 1-Aza-1,3-butadienes
Barluenga, Jose,Aznar, Fernando,Valdes, Carlos,Cabal, Maria-Paz
, p. 6166 - 6171 (2007/10/02)
Catalytic aminomercuration of 3-alken-1-ynes leads to 1-aza-1,3-butadienes and 2-amino-1,3-butadienes.Under appropriate reaction conditions it is possible to prepare these compounds via mercuration of 3-alken-1-ynes in the presence of either aromatic or a
Synthesis of 1-Aza-1,3-dienes and 2-Morpholino-1,3-dienes via Catalytic Aminomercuration of Alk-3-en-1-ynes
Barluenga, Jose,Aznar, Fernando,Liz, Ramon,Cabal, Maria-Paz
, p. 1375 - 1376 (2007/10/02)
Under specific reaction conditions, only the terminal CC triple bond of several alk-3-en-1-ynes adds amines, via catalytic aminomercuration, to afford 1-aza- and 2-morpholino-1,3-dienes.
