66397-26-0Relevant academic research and scientific papers
Microwave promoted rapid isomerisation of propargyl ethers into allenyl ethers
Moghaddam, Firouz Matloubi,Emami, Rahdar
, p. 4073 - 4077 (1997)
Aryl or alkyl propargyl ethers have been isomerized efficiently with good to excellent yield into corresponding allenyl ethers in the presence of potassium tert-butoxide under the microwave irradiation.
Enantioselective Palladium-Catalyzed Hydrophosphinylation of Allenes with Phosphine Oxides: Access to Chiral Allylic Phosphine Oxides
Wang, Jun,Yang, Zhiping
supporting information, p. 27288 - 27292 (2021/11/17)
A Pd-catalyzed hydrophosphinylation of alkyl and aryl-oxyallenes with phosphine oxides has been developed for the efficient and rapid construction of a family of chiral allylic phosphine oxides with a diverse range of functional groups. This methodology was further applied in the facile construction of chiral 2H-chromene and later stage functionalization of cholesterol.
Site-selective and regioselective Diels-Alder reaction of allenyl aryl ethers
Moghaddam, Firouz Matloubi,Kiamehr, Mostafa
experimental part, p. 1333 - 1337 (2011/09/16)
The site-selectivity and regioselectivity of Diels-Alder reactions of allenyl aryl ethers with cyclopentadiene and acrolein were studied. While cyclopentadiene (as an electron-rich diene) only reacted with the external double bond of allenyl aryl ethers t
