66471-65-6Relevant academic research and scientific papers
Ozonides of mono-, bi- and tricyclic terpenes
Griesbaum, Karl,Hilss, Michael,Bosch, Joachim
, p. 14813 - 14826 (2007/10/03)
Ozonolysis of (+)-limonene (1) afforded a monoozonide 2 by attack of ozone at the internal double bond and two diastereomeric diozonides (3). Ozonolysis of 1 on polyethylene gave diozonides 3, and ozonolysis on silica gel gave an epoxy ozonide 5. Ozonolyses of (-)-β-pinene (15), (+)-sabinene (20) and (+)-aromadendrene (23) gave two diastereomers, each, of the corresponding ozonides 16, 21 and 24, respectively. Ozonolysis of camphene (26) gave a very labile ozonide 27, while ozonolysis of (-)-α-pinene (12) gave no ozonide. Ozonolysis of (+)-limonene (1) in the presence of formaldehyde gave a cross-ozonide (4), derived from ozone cleavage of the internal double bond, and ozonolysis of (-)-β-pinene in the presence of acetaldehyde also gave a cross-ozonide (17).
Halogenated Terpenoids. XXI. Concerning endo-2-Chloro-2,3,3-trimethylbicycloheptane (endo-2-Chloro-2,3,3-trimethylnorbornane: endo-Chlorocamphane)
Brecknell, Douglas J.,Carman, Raymond M.,Greenfield, Kay L.
, p. 1075 - 1080 (2007/10/02)
The stability of the title compound is discussed and attempts to synthesize it are described.
