66606-89-1Relevant academic research and scientific papers
Photosensitized Cycloreversion Reactions of Arylated Cage Compounds in Nonpolar Solvents. Highly Efficient Adiabatic Exciplex Isomerization
Hasegawa, Eietsu,Okada, Keiji,Ikeda, Hiroshi,Yamashita, Yoshiro,Mukai, Toshio
, p. 2170 - 2178 (2007/10/02)
Photosensitized cycloreversion reactions of arylated cage compounds 1 to dienes 2 using several cyanoaromatics as sensitizers are reported.In acetonitrile, 1a isomerized to 2a via an efficient cation-radical chain process.In contrast, the isomerizat
Cycloreversion Reaction of Cage Compounds Initiated by Aminium Cation Radical Salts
Hasegawa, Eietsu,Mukai, Toshio
, p. 3391 - 3392 (2007/10/02)
Treating cage compounds 1 with triarylaminium cation radical salts, 3 and 4, resulted in the effective conversion of 1 to dienes 2.The cation radical isomerization induced by electron-transfer from 1 to aminium salt was suggested by the effect of substitu
ELECTRODE-CATALYSED CYCLOREVERSION REACTION OF PHENYLATED BIS-HOMOCUBANES
Takahashi, Yasutake,Sato, Katsuhiro,Miyashi, Tsutomu,Mukai, Toshio
, p. 1553 - 1554 (2007/10/02)
The constant potential anodic oxidation reaction of phenylated bis-homocubanes involved the cycloreversion to give the dienes via a radical chain mechanism.
