6661-03-6Relevant academic research and scientific papers
CoIII-Catalyzed Isonitrile Insertion/Acyl Group Migration Between C?H and N?H bonds of Arylamides
Kalsi, Deepti,Barsu, Nagaraju,Sundararaju, Basker
, p. 2360 - 2364 (2018/02/22)
A general efficient and site-selective cobalt-catalyzed insertion of isonitrile into C?H and N?H bonds of arylamides through C?H bond activation and alcohol assisted intramolecular trans-amidation is demonstrated. This straightforward approach overcomes the limitation by the presence of strongly chelating groups. Isolation of CoIII-isonitrile complex B has been achieved for the first time to understand the reaction mechanism.
Fluorescence of Distyrylbenzenes and Distyrylstilbenes
Erckel, R.,Fruehbeis, H.
, p. 1472 - 1480 (2007/10/02)
Absorption, corrected emission spectra, fluorescence quantum yields, and preparation are reported for distyrylbenzene, distyrylstilbene and substituted derivatives.The Stokes shifts measured in three solvents and correlated with quantum chemical calculations. - Key words: Fluorescence, Distyrylbenzenes
