666749-25-3Relevant academic research and scientific papers
Pd-catalyzed cross-coupling of Baylis-Hillman acetate adducts with bis(pinacolato)diboron: An efficient route to functionalized allyl borates
Kabalka, George W.,Venkataiah, Bollu,Dong, Gang
, p. 5807 - 5809 (2004)
The cross-coupling of Baylis-Hillman acetate adducts and bis(pinacolato)diboron proceeds readily in high yields in the presence of palladium catalyst to produce 3-substituted-2-alkoxycarbonyl allylboronates. These allylboronates can be transformed to stab
Syntheses of β- And γ-fluorophenyl cis- and trans-α-methylene-γ-butyrolactones
Ramachandran, P. Veeraraghavan,Nair, Hari Narayanan G.,Gagare, Pravin
, p. 5722 - 5726 (2015/02/05)
Preparation of a series of cis-γ-fluorophenyl-β-phenyl-α-methylene-γ-butyrolactones is reported via 'allylboration' of fluorobenzaldehydes with (E)-methyl 3-phenyl-2-((4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl)acrylate. The corresponding trans-γ-
Direct synthesis of functionalized allylic boronic esters from allylic alcohols and inexpensive reagents and catalysts
Dutheuil, Guillaume,Selander, Nicklas,Szabo, Kalman J.,Aggarwal, Varinder K.
experimental part, p. 2293 - 2297 (2009/04/06)
A remarkably simple and effective system for the direct conversion of allylic alcohols into high value allylic boronic esters using commercially available reagents and catalysts is described. Georg Thieme Verlag Stuttgart.
SMALL MOLECULES FOR TREATING CANCER AND ABNORMAL CELL PROLIFERATION DISORDERS
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Page/Page column 29-30; 32, (2008/06/13)
Novel compounds and compositions that can be used to bind tubulin, prevent tubulin polymerization, inhibit cell growth, arrest cell cyle, cause cell death, or treat cancer or abnormal cell proliferation disorders. Also disclosed are methods for identifying, synthesizing, and using such compounds.
Novel Functionalized Trisubstituted Allylboronates via Hosomi-Miyaura Borylation of Functionalized Allyl Acetates
Ramachandran, P. Veeraraghavan,Pratihar, Debarshi,Biswas, Debanjan,Srivastava, Amit,Reddy, M. Venkat Ram
, p. 481 - 484 (2007/10/03)
(Equation presented) A series of novel functionalized achiral and chiral allylboronates have been synthesized via the nucleophilic addition of boronates on allyl acetates derived via vinylalumination or Baylis-Hillman reaction of aldehydes. These reagents
