66730-64-1Relevant academic research and scientific papers
Enediolates and dienediolates of carboxylic acids in synthesis. Synthesis of β,γ-epoxyacids from α-chloroketones
Brun, Eva M.,Gil, Salvador,Mestres, Ramon,Parra, Margarita,Villar, Felix
, p. 1055 - 1058 (2007/10/03)
Lithium dienolates of saturated or α,β-unsaturated acids react with α-chloroketones provide a convenient method for preparation of highly sustituted β,γ-epoxyacids. These highly reactive compounds lead in most cases to variable ammounts of the corresponding β-lactones and allylic alcohols.
An Electrochemical Characterization of Dianions: Dilithiated Carboxylic Acids
Renaud, Philippe,Fox, Marye Anne
, p. 5705 - 5709 (2007/10/02)
The oxidation of dilithiated carboxylic acids has been studied by cyclic voltammetry.The pKas for the second deprotonation of phenylacetic acid, diphenylacetic acid, and phenylthioacetic acid have been determined by and equilibration method.Fro
STRUCTURE DU REACTIF D'IVANOV ET DE QUELQUES ORGANOMETALLIQUES ISSUS DES DERIVES PHENYLACETIQUES-II. STEREOCHEMIE DE LA CONDENSATION AVEC LA t-BUTYL-4 CYCLOHEXANONE
Mladenova, M.,Blagoev, B.,Gaudemar, M.,Gaudemar-Bardone, F.,Lallemand, J. Y.
, p. 2157 - 2164 (2007/10/02)
Ivanov reagent and some other analogous reagents (phenyl acetique serie) have been condensed with t-Bu-4 cyclohexanone in order to complete investigation of the reactive species.In all the cases, equatorial attack is highly predominant; it let suppose tha
