6680-06-4

Usage

InChI:InChI=1/C20H22O9/c1-7(21)15(24)19(28)20(29-2)11-5-9-3-8-4-10(22)6-12(23)13(8)17(26)14(9)18(27)16(11)25/h3-4,6-7,11,15-16,20-26H,5H2,1-2H3

Upstream product

• 111468-56-5 Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-3'-methoxy-5',6'--2'-<(carbomethoxymethyl)-4'-<(tert-butyldimethylsilyl)oxy>heptyl>>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate 
• 120264-60-0 6,8,9-Tris-benzyloxymethoxy-3-[(1S,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxa-spiro[4.5]dec-2-yl)-ethyl]-1-oxo-1,2,3,4-tetrahydro-anthracene-2-carboxylic acid methyl ester 
• 111437-04-8 Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-2'-<1-(2-hydroxyethyl)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>heptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate 
• 111436-94-3 Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-3'-methoxy-5',6'--2'-(2-oxoethyl)-4'-<(tert-butyldimethylsilyl)oxy>heptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate 
• 111436-93-2 Methyl 3-<1'-<<2'(R),3'(S),4'(R),5'(S),6'(R)>-3'-methoxy-5',6'--4'-<(tert-butyldimethylsilyl)oxy>-2'-vinylheptyl>>-1,6,8-tris<(benzyloxy)methoxy>-2-naphthoate 
• 111436-95-4 3-<1'-<<1'(S),2'(R),3'(S),4'(R)>-3',4'--1'-methoxy-2'-<(tert-butyldimethylsilyl)oxy>pentyl>>-6,8,9-tris<(benzyloxy)methoxy>-1,2,3,4-tetrahydro-1(2H)-anthracenone 
• 111436-97-6 3-<1'-<<1'(S),2'(R),3'(S),4'(R)>-3',4'--1'-methoxy-2'-oxopentyl>>-6,8,9-tris<(benzyloxy)methoxy>-1,2,3,4-tetrahydro-1(2H)-anthracenone 
• 111436-96-5 3-<1'-<<1'(S),2'(R),3'(S),4'(R)>-3',4'--2'-hydroxy-1'-methoxypentyl>>-6,8,9-tris<(benzyloxy)methoxy>-1,2,3,4-tetrahydro-1(2H)-anthracenone 
• 111436-92-1 methyl 6,8-bis<(benzyloxy)methoxy>-1-hydroxy-3-<(2'R,3'S,4'R,5'S,6'R)-3'-methoxy-5',6'-(cyclohexylidenedioxy)-4'-<(tert-butyldimethylsilyl)oxy>-2'-vinylheptyl>naphthoate 
• 111436-99-8 3-<1'-<<1'(S),2'(R),3'(S),4'(R)>-3',4'--1'-methoxy-2'-oxopentyl>>-6,8,9-tris<(benzyloxy)methoxy>-1,2,3,4-tetrahydro-2-<(tert-butyldimethylsilyl)oxy>-1(2H)-anthracenone 
• 111436-95-4 (R)-6,8,9-Tris-benzyloxymethoxy-3-[(1S,2R)-2-(tert-butyl-dimethyl-silanyloxy)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxa-spiro[4.5]dec-2-yl)-ethyl]-3,4-dihydro-2H-anthracen-1-one 
• 111436-97-6 (R)-6,8,9-Tris-benzyloxymethoxy-3-[(S)-1-methoxy-2-((2S,3R)-3-methyl-1,4-dioxa-spiro[4.5]dec-2-yl)-2-oxo-ethyl]-3,4-dihydro-2H-anthracen-1-one 
• 111436-96-5 (R)-6,8,9-Tris-benzyloxymethoxy-3-[(1S,2R)-2-hydroxy-1-methoxy-2-((2R,3R)-3-methyl-1,4-dioxa-spiro[4.5]dec-2-yl)-ethyl]-3,4-dihydro-2H-anthracen-1-one 
• 111436-91-0 5,7-Bis-benzyloxymethoxy-3H-isobenzofuran-1-one 

Relevant academic research and scientific papers

A highly stereoselective synthesis of (+)-olivin, the aglycon of olivomycin A

The first total synthesis of (+)-olivin (1), the naturally occurring enantiomer of the aglycon of olivomycin A, is described. The synthesis is highly stereoselective, featuring the reaction of (γ-methoxyallyl)boronate 21 with chiral aldehyde 17 and the ad