66807-76-9Relevant academic research and scientific papers
Re-entry of tin in N-alkylation: First example of a homogeneous heterobimetallic Pd-Sn catalyst for base and additive free alkylation of amine and surrogates with alcohol
Mohanty, Anuradha,Roy, Sujit
, p. 2749 - 2753 (2016)
The N-alkylation of amines, and amides with benzyl alcohols is catalyzed by bimetallic catalyst [Pd(COD)(SnCl3)Cl] in o-xylene. The reaction does not require additional base, additive or ligand, and is insensitive toward air and moisture and involves minimal work-up. These features make the reaction attractive, simple, and practical.
First example of a heterobimetallic 'Pd-Sn' catalyst for direct activation of alcohol: Efficient allylation, benzylation and propargylation of arenes, heteroarenes, active methylenes and allyl-Si nucleophiles
Das, Debjit,Pratihar, Sanjay,Roy, Ujjal Kanti,Mal, Dipakranjan,Roy, Sujit
, p. 4537 - 4542 (2012/07/17)
Arenes, heteroarenes, 1,3-dicarbonyls and organosilicon nucleophiles undergo highly efficient alkylation with allylic, propargylic and benzylic alcohols in the presence of a new 'Pd-Sn' bimetallic catalyst in nitromethane; water being the sole byproduct.
Heterobimetallic Pd-Sn catalysis: A Suzuki, tandem ring-closing sequence toward indeno[2,1-b]thiophenes and indeno[2,1-b]indoles
Das, Debjit,Pratihar, Sanjay,Roy, Sujit
supporting information, p. 4870 - 4873,4 (2020/09/16)
Indeno[2,1-b]thiophene and indeno[1,2-b]indole motifs have been obtained in moderate to good yields from easily available substituted boronic acids, 2-bromo aryl/vinyl aldehydes, and nucleophiles such as arenes/heteroarenes and others using a catalytic co
