66809-32-3

Basic information

• Product Name: N-(5-nitro-1-oxypyridin-2-yl)aniline
• Synonyms: N-(5-nitro-1-oxypyridin-2-yl)aniline
• CAS NO: 66809-32-3
• Molecular Weight: 231.211
• Mol File: 66809-32-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(5-nitro-1-oxypyridin-2-yl)aniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-(5-nitro-1-oxypyridin-2-yl)aniline(66809-32-3)
• EPA Substance Registry System: N-(5-nitro-1-oxypyridin-2-yl)aniline(66809-32-3)

Safety Data

• Hazardous Substances Data: 66809-32-3(Hazardous Substances Data)

Upstream product

• 62-53-3 aniline 
• 2530-26-9 3-nitropyridine 
• 6825-25-8 5-nitro-N-phenylpyridin-2-amine 

Relevant articles and documents

S NH Arylamination of 3-Nitropyridine: A Competitive Formation of 2-Arylamino-5-nitropyridines and 2-Arylamino-5-nitrosopyridines

Arylamination of 3-nitropyridine via the nucleophilic substitution of hydrogen leads to a mixture of 2-arylamino-5-nitropyridines and novel 2-arylamino-5-nitrosopyridines, with the latter as the major product. The proposed mechanism includes the formation of σ H -adducts and their further aromatization proceeding either through an oxidative pathway or intramolecular Red/Ox pathway of the S NH reaction. Moreover, we have shown that nitroso compounds can be selectively oxidized with m -chloroperbenzoic acid to give the corresponding nitro derivatives or their N -oxides, depending on the reaction temperature and the amount of oxidant.