66874-49-5

Upstream product

• 1463-04-3 (3-methylbut-3-en-1-ynyl)benzene 
• 811-49-4 ethyllithium 
• 536-74-3 phenylacetylene 
• 41793-37-7 (-)-(R)-1-bromo-3-methyl-1,2-hexadiene 
• 100-52-7 benzaldehyde 

Relevant academic research and scientific papers

REACTIONS OF 3-ALKYL- AND 3,3-DIALKYL-1-BROMOALLENES WITH ORGANOCUPRATES: EFFECTS OF THE NATURE OF THE CUPRATE REAGENT ON THE REGIO- AND STEREOSELECTIVITY

Organocuprates induce 1,3- and direct substitution in 3-alkyl- and 3,3-dialkyl-1-bromo-1,2-dienes leading respectively to either terminal acetylenes or allenic hydrocarbons.The nature of the cuprate exerts a prominent role in determining both the regio- and the stereochemistry of these reactions.